Preparation of supported mesoporous thin films concerning template removal by supercritical fluid extraction

Thin films of silicate MCM-41 and silicate MCM-48 have been prepared on porous ceramic supports by the hydrothermal method. A comparative study of template removal has been made on supported thin films and on powder. By supercritical fluid extraction (SFE) with CH(3)OH-modified CO(2), at least 78% o...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 21(2005), 4 vom: 15. Feb., Seite 1171-4
1. Verfasser: Huang, L (VerfasserIn)
Weitere Verfasser: Poh, C, Ng, S C, Hidajat, K, Kawi, S
Format: Aufsatz
Sprache:English
Veröffentlicht: 2005
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Letter
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245 1 0 |a Preparation of supported mesoporous thin films concerning template removal by supercritical fluid extraction 
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520 |a Thin films of silicate MCM-41 and silicate MCM-48 have been prepared on porous ceramic supports by the hydrothermal method. A comparative study of template removal has been made on supported thin films and on powder. By supercritical fluid extraction (SFE) with CH(3)OH-modified CO(2), at least 78% of the template can be removed from as-synthesized materials at 85 degrees C. X-ray diffraction (XRD) observations indicate that the resulting supported thin films after SFE are structurally stable and ordered with a weak pore contraction. The advantages of SFE over calcination in template removal are presented with a series of results obtained on supported thin films and on powder by XRD and N(2) adsorption-desorption 
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700 1 |a Poh, C  |e verfasserin  |4 aut 
700 1 |a Ng, S C  |e verfasserin  |4 aut 
700 1 |a Hidajat, K  |e verfasserin  |4 aut 
700 1 |a Kawi, S  |e verfasserin  |4 aut 
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