Total NMR assignments of new [C7-O-C7'']-biflavones from leaves of the limonene-carvone chemotype of Lippia alba (Mill) N. E. Brown

Copyright (c) 2005 John Wiley & Sons, Ltd

Bibliographische Detailangaben
Veröffentlicht in:Magnetic resonance in chemistry : MRC. - 1985. - 43(2005), 4 vom: 23. Apr., Seite 334-8
1. Verfasser: Barbosa, Francisco Geraldo (VerfasserIn)
Weitere Verfasser: Lima, Mary Anne Sousa, Silveira, Edilberto Rocha
Format: Aufsatz
Sprache:English
Veröffentlicht: 2005
Zugriff auf das übergeordnete Werk:Magnetic resonance in chemistry : MRC
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Biflavonoids Cyclohexane Monoterpenes Cyclohexenes Monoterpenes Terpenes carvone 75GK9XIA8I Limonene 9MC3I34447
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520 |a Phytochemical analysis of leaves of the limonene-carvone chemotype of Lippia alba led to the isolation of two biflavonoids with a new structural pattern with an ether linkage: 5,5''-dihydroxy-6,4',6'',3''',4'''-pentamethoxy-[C(7)--O--C(7'')]-biflavone (1) and 4',4,5,5''-tetrahydroxy-6,6'',3'''-trimethoxy-[C(7)--O--C(7'')]-biflavone (2). Structural elucidation of the new compounds was established on the basis of spectral data, through the use of 1D NMR and several 2D shift correlated NMR pulse sequences (COSY, HMQC, HMBC and NOESY) 
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