Synthesis and optical properties of thiol-stabilized PbS nanocrystals

Thiol-capped water-soluble PbS nanocrystals (NCs) stabilized with 1-thioglycerol, dithioglycerol, or a mixture of 1-thioglycerol/dithioglycerol (TGL/DTG) were prepared via one-stage synthesis at room temperature. We found that NCs stabilized with a TGL/DTG mixture show efficient and stable infrared...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 21(2005), 3 vom: 01. Feb., Seite 1086-90
1. Verfasser: Zhao, Xusheng (VerfasserIn)
Weitere Verfasser: Gorelikov, Ivan, Musikhin, Sergei, Cauchi, Sam, Sukhovatkin, Vlad, Sargent, Edward H, Kumacheva, Eugenia
Format: Aufsatz
Sprache:English
Veröffentlicht: 2005
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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245 1 0 |a Synthesis and optical properties of thiol-stabilized PbS nanocrystals 
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520 |a Thiol-capped water-soluble PbS nanocrystals (NCs) stabilized with 1-thioglycerol, dithioglycerol, or a mixture of 1-thioglycerol/dithioglycerol (TGL/DTG) were prepared via one-stage synthesis at room temperature. We found that NCs stabilized with a TGL/DTG mixture show efficient and stable infrared photoluminescence centered in the second "biological window" (1050-1200 nm). Under optimized conditions, full width at half-maximum of the PL emission peak was from 70 to 100 nm. PbS NCs were stable to precipitation and aggregation for the time period from 2 to 3 months when stored in the dark under room temperature. Room-temperature photoluminescence quantum efficiency of NCs was from 7 to 10%. When NCs were stored at 37 degrees C, their PL emission red-shifted, consistent with the NC growth 
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700 1 |a Gorelikov, Ivan  |e verfasserin  |4 aut 
700 1 |a Musikhin, Sergei  |e verfasserin  |4 aut 
700 1 |a Cauchi, Sam  |e verfasserin  |4 aut 
700 1 |a Sukhovatkin, Vlad  |e verfasserin  |4 aut 
700 1 |a Sargent, Edward H  |e verfasserin  |4 aut 
700 1 |a Kumacheva, Eugenia  |e verfasserin  |4 aut 
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