X-ray photoelectron spectroscopy and near-edge X-ray absorption fine structure study of water adsorption on pyridine-terminated thiolate self-assembled monolayers

Adsorption of water on self-assembled monolayers (SAMs) of 4-(4-mercaptophenyl)pyridine on gold at low temperatures under ultrahigh vacuum conditions is studied by synchrotron radiation X-ray photoelectron and absorption spectroscopy. Water adsorption induces a strong modification of the chemical st...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 20(2004), 25 vom: 07. Dez., Seite 11022-9
1. Verfasser: Zubavichus, Yan (VerfasserIn)
Weitere Verfasser: Zharnikov, Michael, Yang, Yongjie, Fuchs, Oliver, Umbach, Eberhard, Heske, Clemens, Ulman, Abraham, Grunze, Michael
Format: Aufsatz
Sprache:English
Veröffentlicht: 2004
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, Non-U.S. Gov't 4-(4-mercaptophenyl)pyridine Membranes, Artificial Pyridines Sulfhydryl Compounds Water 059QF0KO0R Gold 7440-57-5
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245 1 0 |a X-ray photoelectron spectroscopy and near-edge X-ray absorption fine structure study of water adsorption on pyridine-terminated thiolate self-assembled monolayers 
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520 |a Adsorption of water on self-assembled monolayers (SAMs) of 4-(4-mercaptophenyl)pyridine on gold at low temperatures under ultrahigh vacuum conditions is studied by synchrotron radiation X-ray photoelectron and absorption spectroscopy. Water adsorption induces a strong modification of the chemical state of the pyridine N atoms at the SAM/ice interface, indicative for strong H bonding and partial proton transfer between water molecules and pyridine moieties. Additionally, the initial molecular orientation within the SAM is changed upon formation of an adsorbed water multilayer 
650 4 |a Journal Article 
650 4 |a Research Support, Non-U.S. Gov't 
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650 7 |a Membranes, Artificial  |2 NLM 
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650 7 |a 059QF0KO0R  |2 NLM 
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700 1 |a Zharnikov, Michael  |e verfasserin  |4 aut 
700 1 |a Yang, Yongjie  |e verfasserin  |4 aut 
700 1 |a Fuchs, Oliver  |e verfasserin  |4 aut 
700 1 |a Umbach, Eberhard  |e verfasserin  |4 aut 
700 1 |a Heske, Clemens  |e verfasserin  |4 aut 
700 1 |a Ulman, Abraham  |e verfasserin  |4 aut 
700 1 |a Grunze, Michael  |e verfasserin  |4 aut 
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