Preparation of microcapsules containing two-phase core materials

Urea-formaldehyde (UF) microcapsules containing two-phase core materials in which phthalocyanine blue BGS (beta-CuPc) particles were homodispersed in tetrachloroethylene (TCE) were prepared by in situ polymerization. The effects of the various process parameters, including the type of surface modifi...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 20(2004), 25 vom: 07. Dez., Seite 10845-50
1. Verfasser: Wang, Jian-Ping (VerfasserIn)
Weitere Verfasser: Zhao, Xiao-Peng, Guo, Hui-Lin, Zheng, Qing
Format: Aufsatz
Sprache:English
Veröffentlicht: 2004
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Amines Capsules Indoles Organometallic Compounds Surface-Active Agents Formaldehyde 1HG84L3525 copper phthalocyanine mehr... 3VEX9T7UT5 Urea 8W8T17847W stearylamine FFV58UNY7O Tetrachloroethylene TJ904HH8SN
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520 |a Urea-formaldehyde (UF) microcapsules containing two-phase core materials in which phthalocyanine blue BGS (beta-CuPc) particles were homodispersed in tetrachloroethylene (TCE) were prepared by in situ polymerization. The effects of the various process parameters, including the type of surface modifier, the viscosity of UF prepolymer, the type of water-soluble surfactant, and the concentration of oil-soluble surfactant in the capsule core on the dispersity of beta-CuPc particles in TCE and the properties of the capsule wall and the adsorption of beta-CuPc particles on the internal surface of capsule wall were experimentally investigated. It was shown that using octadecylamine (ODA) to modify beta-CuPc particles resulted in a significant increase of the dispersing extent (DE) and the electrophoresis velocity of the particles in TCE (about 4 and 20 times more than that of unmodified). In addition, the optimal reaction conditions of the synthesis UF prepolymer were obtained by the orthogonal test. On the other hand, as the oil/water interfacial tension of emulsion was big enough, the microcapsule formed. The concentration of Span-80 in TCE was no less than 0.062 mM; the adsorption of beta-CuPc particles on internal surface of wall were restrained. Finally, the microcapsules in which beta-CuPc particles possess reversible response to dc electric field were obtained 
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700 1 |a Zhao, Xiao-Peng  |e verfasserin  |4 aut 
700 1 |a Guo, Hui-Lin  |e verfasserin  |4 aut 
700 1 |a Zheng, Qing  |e verfasserin  |4 aut 
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