|
|
|
|
| LEADER |
01000naa a22002652 4500 |
| 001 |
NLM152122621 |
| 003 |
DE-627 |
| 005 |
20231223061357.0 |
| 007 |
tu |
| 008 |
231223s2004 xx ||||| 00| ||eng c |
| 028 |
5 |
2 |
|a pubmed24n0507.xml
|
| 035 |
|
|
|a (DE-627)NLM152122621
|
| 035 |
|
|
|a (NLM)15544384
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Tzvetkov, G
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a Bonding and structure of glycine on ordered Al2O3 film surfaces
|
| 264 |
|
1 |
|c 2004
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ohne Hilfsmittel zu benutzen
|b n
|2 rdamedia
|
| 338 |
|
|
|a Band
|b nc
|2 rdacarrier
|
| 500 |
|
|
|a Date Completed 24.04.2006
|
| 500 |
|
|
|a Date Revised 21.11.2013
|
| 500 |
|
|
|a published: Print
|
| 500 |
|
|
|a Citation Status MEDLINE
|
| 520 |
|
|
|a The interaction between glycine (NH2CH2COOH) layers and an ultrathin Al2O3 film grown epitaxially onto NiAl(110) was studied by temperature-programmed desorption, X-ray photoelectron spectroscopy, ultraviolet photoelectron spectroscopy, work function measurements, and near-edge X-ray absorption fine structure (NEXAFS) spectroscopy. At monolayer coverages at 110 K, there are two coexisting molecular forms: the anionic (NH2CH2COO-) and the zwitterionic form (NH3+CH2COO-) of glycine. As deduced from the photoemission data, the buildup of multilayers at 110 K leads to a condensed phase predominantly in the zwitterionic state. In contrast to the monolayer at 110 K, the monolayer formed at 300 K consists primarily of glycine molecules in the anionic state. The latter species is adsorbed with the oxygen atoms of the carboxylic group pointing toward the substrate. The polarization-dependent C K- and O K-edge NEXAFS spectra indicate that the glycinate species in the monolayer at 300 K is oriented nearly perpendicular to the surface, with the amino group pointing away from the surface
|
| 650 |
|
4 |
|a Journal Article
|
| 650 |
|
4 |
|a Research Support, Non-U.S. Gov't
|
| 650 |
|
7 |
|a Membranes, Artificial
|2 NLM
|
| 650 |
|
7 |
|a Aluminum Oxide
|2 NLM
|
| 650 |
|
7 |
|a LMI26O6933
|2 NLM
|
| 650 |
|
7 |
|a Glycine
|2 NLM
|
| 650 |
|
7 |
|a TE7660XO1C
|2 NLM
|
| 700 |
1 |
|
|a Koller, G
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Zubavichus, Y
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Fuchs, O
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Casu, M B
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Heske, C
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Umbach, E
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Grunze, M
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Ramsey, M G
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Netzer, F P
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 20(2004), 24 vom: 23. Nov., Seite 10551-9
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
|
| 773 |
1 |
8 |
|g volume:20
|g year:2004
|g number:24
|g day:23
|g month:11
|g pages:10551-9
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_22
|
| 912 |
|
|
|a GBV_ILN_350
|
| 912 |
|
|
|a GBV_ILN_721
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 20
|j 2004
|e 24
|b 23
|c 11
|h 10551-9
|