Dynamic surface properties of poly(N-isopropylacrylamide) solutions

The dynamic surface elasticity of aqueous solutions of poly(N-isopropylacrylamide) (pNIPAM) has been measured by the oscillating barrier and capillary wave methods as a function of time and concentration. While the real and imaginary parts of the surface elasticity almost did not change with the con...

Ausführliche Beschreibung

Bibliographische Detailangaben
Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1991. - 20(2004), 22 vom: 26. Okt., Seite 9669-76
1. Verfasser: Noskov, B A (VerfasserIn)
Weitere Verfasser: Akentiev, A V, Bilibin, A Yu, Grigoriev, D O, Loglio, G, Zorin, I M, Miller, R
Format: Aufsatz
Sprache:English
Veröffentlicht: 2004
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
LEADER 01000caa a22002652 4500
001 NLM151621799
003 DE-627
005 20250205225658.0
007 tu
008 231223s2004 xx ||||| 00| ||eng c
028 5 2 |a pubmed25n0506.xml 
035 |a (DE-627)NLM151621799 
035 |a (NLM)15491201 
040 |a DE-627  |b ger  |c DE-627  |e rakwb 
041 |a eng 
100 1 |a Noskov, B A  |e verfasserin  |4 aut 
245 1 0 |a Dynamic surface properties of poly(N-isopropylacrylamide) solutions 
264 1 |c 2004 
336 |a Text  |b txt  |2 rdacontent 
337 |a ohne Hilfsmittel zu benutzen  |b n  |2 rdamedia 
338 |a Band  |b nc  |2 rdacarrier 
500 |a Date Completed 26.05.2006 
500 |a Date Revised 19.10.2004 
500 |a published: Print 
500 |a Citation Status PubMed-not-MEDLINE 
520 |a The dynamic surface elasticity of aqueous solutions of poly(N-isopropylacrylamide) (pNIPAM) has been measured by the oscillating barrier and capillary wave methods as a function of time and concentration. While the real and imaginary parts of the surface elasticity almost did not change with the concentration, their kinetic dependencies proved to be nonmonotonic. Simultaneous measurements of the film thickness and adsorbed amount by null-ellipsometry showed that the pNIPAM adsorption can be divided into two steps corresponding to the formation of a concentrated narrow region close to the air phase and a region of tails and loops protruding into the bulk liquid. The local maximum of the elasticity can be observed in the course of the first step when the adsorbed macromolecules do not form long loops and tails. The results are in agreement with recent data on the nonequilibrium surface properties of solutions of other nonionic homopolymers and the theory of dilational surface viscoelasticity 
650 4 |a Journal Article 
700 1 |a Akentiev, A V  |e verfasserin  |4 aut 
700 1 |a Bilibin, A Yu  |e verfasserin  |4 aut 
700 1 |a Grigoriev, D O  |e verfasserin  |4 aut 
700 1 |a Loglio, G  |e verfasserin  |4 aut 
700 1 |a Zorin, I M  |e verfasserin  |4 aut 
700 1 |a Miller, R  |e verfasserin  |4 aut 
773 0 8 |i Enthalten in  |t Langmuir : the ACS journal of surfaces and colloids  |d 1991  |g 20(2004), 22 vom: 26. Okt., Seite 9669-76  |w (DE-627)NLM098181009  |x 0743-7463  |7 nnns 
773 1 8 |g volume:20  |g year:2004  |g number:22  |g day:26  |g month:10  |g pages:9669-76 
912 |a GBV_USEFLAG_A 
912 |a SYSFLAG_A 
912 |a GBV_NLM 
912 |a GBV_ILN_22 
912 |a GBV_ILN_350 
912 |a GBV_ILN_721 
951 |a AR 
952 |d 20  |j 2004  |e 22  |b 26  |c 10  |h 9669-76