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|a (NLM)15379518
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|a DE-627
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|e rakwb
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|a eng
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|a Tang, Shijun
|e verfasserin
|4 aut
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|a Crystallization kinetics of thermosensitive colloids probed by transmission spectroscopy
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|c 2004
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|a Text
|b txt
|2 rdacontent
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|a ohne Hilfsmittel zu benutzen
|b n
|2 rdamedia
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|a Band
|b nc
|2 rdacarrier
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|a Date Completed 21.08.2006
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|a Date Revised 15.11.2006
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|a published: Print
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|a Citation Status PubMed-not-MEDLINE
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|a The kinetics of crystallization of poly-N-isopropylacrylamide (PNIPAM) particles has been investigated using the UV-visible transmission spectroscopy. Since the particle size decreases with the increase in temperature, microgel dispersions of different volume fractions have been obtained by varying the temperature of a single sample. It is found that the rates of the change in crystallinity, the average crystallite size, and the number density of crystallites at the most rapid stage over a certain time interval at various temperatures can be described by the power-law relations. At 19 degrees C, the PNIPAM system behaves as a hard sphere system under microgravity. The hard sphere theory based on Monte Carlo simulation has been used as a reference point to compare with conventional hard spheres, soft spheres, and PNIPAM spheres
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|a Journal Article
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|a Research Support, U.S. Gov't, Non-P.H.S.
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|a Hu, Zhibing
|e verfasserin
|4 aut
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|a Cheng, Zhengdong
|e verfasserin
|4 aut
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|a Wu, Jianzhong
|e verfasserin
|4 aut
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 20(2004), 20 vom: 28. Sept., Seite 8858-64
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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|g volume:20
|g year:2004
|g number:20
|g day:28
|g month:09
|g pages:8858-64
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|d 20
|j 2004
|e 20
|b 28
|c 09
|h 8858-64
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