|
|
|
|
| LEADER |
01000naa a22002652 4500 |
| 001 |
NLM150414463 |
| 003 |
DE-627 |
| 005 |
20231223053816.0 |
| 007 |
tu |
| 008 |
231223s2004 xx ||||| 00| ||eng c |
| 028 |
5 |
2 |
|a pubmed24n0502.xml
|
| 035 |
|
|
|a (DE-627)NLM150414463
|
| 035 |
|
|
|a (NLM)15366060
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Vinklárek, Jaromír
|e verfasserin
|4 aut
|
| 245 |
1 |
3 |
|a An experimental and theoretical study of the Cp2VO2CO
|b use of 13CO3(2-) for structure investigation of d1-metallocene complexes
|
| 264 |
|
1 |
|c 2004
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ohne Hilfsmittel zu benutzen
|b n
|2 rdamedia
|
| 338 |
|
|
|a Band
|b nc
|2 rdacarrier
|
| 500 |
|
|
|a Date Completed 17.03.2005
|
| 500 |
|
|
|a Date Revised 16.11.2017
|
| 500 |
|
|
|a published: Print
|
| 500 |
|
|
|a Citation Status MEDLINE
|
| 520 |
|
|
|a Copyright 2004 John Wiley & Sons, Ltd.
|
| 520 |
|
|
|a EPR study has shown that the anticancer agent vanadocene dichloride (Cp2VCl2) interacts with carbonate contained in physiological solutions. Chelate complex Cp2VO2CO (|A(iso)(51V)| = 175.1 MHz, g(iso) = 1.9861) is the only paramagnetic species formed in the range about the physiological pH (5.5-11.0). The super-hyperfine coupling (|a(iso)(13C)| = 24.1 MHz) was evidenced at measurements using 13C labelled carbonate. The structure of carbonate complex was validated by comparison of observed and theoretical calculated HFC tensors (at the density functional level of theory)
|
| 650 |
|
4 |
|a Journal Article
|
| 650 |
|
4 |
|a Research Support, Non-U.S. Gov't
|
| 650 |
|
7 |
|a Carbon Isotopes
|2 NLM
|
| 650 |
|
7 |
|a Carbonates
|2 NLM
|
| 650 |
|
7 |
|a Organometallic Compounds
|2 NLM
|
| 650 |
|
7 |
|a Vanadium Compounds
|2 NLM
|
| 650 |
|
7 |
|a metallocene
|2 NLM
|
| 650 |
|
7 |
|a vanadocene dichloride
|2 NLM
|
| 650 |
|
7 |
|a 4W2E0IDO21
|2 NLM
|
| 700 |
1 |
|
|a Honzícek, Jan
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Holubová, Jana
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Magnetic resonance in chemistry : MRC
|d 1985
|g 42(2004), 10 vom: 18. Okt., Seite 870-4
|w (DE-627)NLM098179667
|x 1097-458X
|7 nnns
|
| 773 |
1 |
8 |
|g volume:42
|g year:2004
|g number:10
|g day:18
|g month:10
|g pages:870-4
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_350
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 42
|j 2004
|e 10
|b 18
|c 10
|h 870-4
|