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231223s2004 xx ||||| 00| ||eng c |
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|a DE-627
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|e rakwb
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|a eng
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|a Nagasawa, Jun'ichi
|e verfasserin
|4 aut
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|a Organogelation of diacetylene cholesteryl esters having two urethane linkages and their photopolymerization in the gel state
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|c 2004
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|a Text
|b txt
|2 rdacontent
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|a ohne Hilfsmittel zu benutzen
|b n
|2 rdamedia
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|2 rdacarrier
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|a Date Completed 13.06.2006
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|a Date Revised 21.11.2013
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|a published: Print
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|a Citation Status MEDLINE
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|a Various diacetylene cholesteryl esters having two urethane linkages were synthesized to study the relationship between their gelation properties and chemical structures. Most of these compounds form organogels in cyclohexane, and some compounds gelatinized hexane, diethyl ether, N,N-dimethylformamide, and ethanol. The cholesteryl moieties play an important role in gel formation, but IR spectroscopic measurements show that the main driving force for gelation is hydrogen bonding of the urethane groups. Upon UV irradiation, most of the gels polymerized to give polydiacetylenes, with concomitant changes from colorless to a variety of hues, such as dark blue, orange, and pink. The polymerization proceeds efficiently in cases where the gels change color to dark blue. The polymerization reached 52% chemical yield, with the quantum yield estimated to be at least 54. Solid-state NMR spectroscopy confirmed that polymerization in the gel state proceeds via 1,4-addition
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|a Journal Article
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|a Cholesterol Esters
|2 NLM
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|a Gels
|2 NLM
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|a Urethane
|2 NLM
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|a 3IN71E75Z5
|2 NLM
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|a Acetylene
|2 NLM
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|a OC7TV75O83
|2 NLM
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|a Kudo, Masabumi
|e verfasserin
|4 aut
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|a Hayashi, Shigenobu
|e verfasserin
|4 aut
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|a Tamaoki, Nobuyuki
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1991
|g 20(2004), 19 vom: 14. Sept., Seite 7907-16
|w (DE-627)NLM098181009
|x 0743-7463
|7 nnns
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| 773 |
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|g volume:20
|g year:2004
|g number:19
|g day:14
|g month:09
|g pages:7907-16
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