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231223s2004 xx ||||| 00| ||eng c |
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|a pubmed24n0500.xml
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|a (DE-627)NLM149874103
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|a (NLM)15307065
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|a DE-627
|b ger
|c DE-627
|e rakwb
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|a eng
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| 100 |
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|a Eichele, Klaus
|e verfasserin
|4 aut
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| 245 |
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|a A simple molecule with a complex crystal structure
|b interplay of 31P solid-state NMR spectroscopy and single-crystal x-ray diffraction in the structure determination of a ruthenium diphosphine diamine complex
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|c 2004
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|a Text
|b txt
|2 rdacontent
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|a ohne Hilfsmittel zu benutzen
|b n
|2 rdamedia
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| 338 |
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|a Band
|b nc
|2 rdacarrier
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| 500 |
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|a Date Completed 16.03.2005
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|a Date Revised 21.11.2013
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|a published: Print
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|a Citation Status MEDLINE
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| 520 |
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|a 2004 John Wiley & Sons, Ltd.
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|a A comprehensive 31P solid-state NMR study of Ru(eta1-Ph2PCH2CH2OCH3)2(eta2-en)Cl2 (en = ethylenediamine) (1), by 1D (contact time variation, inversion-recovery, SPARTAN) and 2D techniques (homonuclear J-resolved, SECSY) indicated that the crystal structure of 1 should be complex. The single-crystal x-ray structure determination confirmed the presence of eight independent molecules in the asymmetric unit, with 31P isotropic chemical shifts in the range 27.3-40.1 ppm, while the spans of the phosphorus chemical shift tensors are of the order of 170 ppm. Based on unique structural features and NMR data, one molecule has been tentatively assigned
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|a Comparative Study
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|a Journal Article
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|a Research Support, Non-U.S. Gov't
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| 650 |
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|a Diamines
|2 NLM
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| 650 |
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|a Phosphines
|2 NLM
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| 650 |
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|a Powders
|2 NLM
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| 650 |
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|a Phosphorus
|2 NLM
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| 650 |
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|a 27YLU75U4W
|2 NLM
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| 650 |
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|a Ruthenium
|2 NLM
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| 650 |
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7 |
|a 7UI0TKC3U5
|2 NLM
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| 700 |
1 |
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|a Nachtigal, Christiane
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Jung, Susanne
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Mayer, Hermann A
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Lindner, Ekkehard
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Ströbele, Markus
|e verfasserin
|4 aut
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| 773 |
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8 |
|i Enthalten in
|t Magnetic resonance in chemistry : MRC
|d 1985
|g 42(2004), 9 vom: 15. Sept., Seite 807-13
|w (DE-627)NLM098179667
|x 1097-458X
|7 nnns
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| 773 |
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|g volume:42
|g year:2004
|g number:9
|g day:15
|g month:09
|g pages:807-13
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