Metallic nanoparticle production utilizing a supercritical carbon dioxide flow process

Metallic nanoparticles of palladium and silver ranging in size from 1 to 15 nm were produced entirely within carbon dioxide by spraying a carbon dioxide carrier solution containing CO2-soluble metal precursors into a CO2 receiving solution containing a reducing agent (NaBH(OAc)3 or H2) and fluorocar...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 20(2004), 17 vom: 17. Aug., Seite 7078-82
1. Verfasser: McLeod, M Chandler (VerfasserIn)
Weitere Verfasser: Gale, William F, Roberts, Christopher B
Format: Aufsatz
Sprache:English
Veröffentlicht: 2004
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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520 |a Metallic nanoparticles of palladium and silver ranging in size from 1 to 15 nm were produced entirely within carbon dioxide by spraying a carbon dioxide carrier solution containing CO2-soluble metal precursors into a CO2 receiving solution containing a reducing agent (NaBH(OAc)3 or H2) and fluorocarbon thiol stabilizing ligands. The process uses the benign solvent CO2 while also allowing for the production of nanoparticles with a limited number of chemical components. Particles were characterized by transmission electron microscopy (TEM) and energy dispersive spectroscopy (EDS) 
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700 1 |a Roberts, Christopher B  |e verfasserin  |4 aut 
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