Improving the two-step remediation process for CCA-treated wood : Part II. Evaluating bacterial nutrient sources

Remediation processes for recovery and reuse of chromated-copper-arsenate- (CCA) treated wood are not gaining wide acceptance because they are more expensive than landfill disposal. One reason is the high cost of the nutrient medium used to culture the metal-tolerant bacterium, Bacillus licheniformi...

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Publié dans:Waste management (New York, N.Y.). - 1999. - 24(2004), 4 vom: 03., Seite 407-11
Auteur principal: Clausen, Carol A (Auteur)
Format: Article
Langue:English
Publié: 2004
Accès à la collection:Waste management (New York, N.Y.)
Sujets:Journal Article Arsenates Chromium 0R0008Q3JB chromated copper arsenate 37337-13-6 Copper 789U1901C5 Oxalic Acid 9E7R5L6H31 plus... Arsenic N712M78A8G
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245 1 0 |a Improving the two-step remediation process for CCA-treated wood  |b Part II. Evaluating bacterial nutrient sources 
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520 |a Remediation processes for recovery and reuse of chromated-copper-arsenate- (CCA) treated wood are not gaining wide acceptance because they are more expensive than landfill disposal. One reason is the high cost of the nutrient medium used to culture the metal-tolerant bacterium, Bacillus licheniformis, which removes 70-100% of the copper, chromium, and arsenic from CCA-treated southern yellow pine (CCA-SYP) in a two-step process involving oxalic acid extraction and bacterial culture. To reduce this cost, the nutrient concentration in the culture medium and the ratio of wood to nutrient medium were optimized. Maximum metal removal occurred when B. licheniformis was cultured in 1.0% nutrient medium and at a wood to nutrient medium ratio of 1:10. Also, malted barley, an abundant by-product of brewing, was evaluated as an alternative nutrient medium. Tests were done to determine absorption of metals by barley, and the results indicate that the barley acted as a biosorbent, removing heavy metals from the liquid culture after their release from CCA to SYP. For comparison, tests were also performed with no nutrient medium. Following bacterial remediation, 17% copper and 15% arsenic were removed from an aqueous slurry of CCA-SYP (no medium). When oxalic acid extraction preceded the aqueous bacterial culture, 21% copper, 54% chromium, and 63% arsenic were removed. The two-step process (oxalic acid extraction and bacterial culture with nutrient medium) appears to be an effective, yet costly, way to remove metals 
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650 7 |a chromated copper arsenate  |2 NLM 
650 7 |a 37337-13-6  |2 NLM 
650 7 |a Copper  |2 NLM 
650 7 |a 789U1901C5  |2 NLM 
650 7 |a Oxalic Acid  |2 NLM 
650 7 |a 9E7R5L6H31  |2 NLM 
650 7 |a Arsenic  |2 NLM 
650 7 |a N712M78A8G  |2 NLM 
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