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231222s2001 xx ||||| 00| ||eng c |
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|a pubmed25n0386.xml
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|a (DE-627)NLM115742107
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|a (NLM)11679770
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|a DE-627
|b ger
|c DE-627
|e rakwb
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|a eng
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|a Dova, E
|e verfasserin
|4 aut
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|a Structure determination of two metal-organic complexes from high-resolution synchrotron powder diffraction data
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|c 2001
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|a Text
|b txt
|2 rdacontent
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|a ohne Hilfsmittel zu benutzen
|b n
|2 rdamedia
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|a Band
|b nc
|2 rdacarrier
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|a Date Completed 14.01.2002
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|a Date Revised 05.06.2019
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a The crystal structures of [1,2-bis(2,6-diisopropylphenylimino)acenaphthene-N,N']carbonylchlororhodium(I) (1) and [N,N'-ethylene-bis(3-methylsalicylideneiminato)-O,N,N',O'](tetrahydrofurfuryl)-cobalt(II) (2) have been determined from high-resolution synchrotron X-ray powder diffraction data. Compound 1 is the first neutral Rh complex, in contrast with findings in the literature, containing a bidentate nitrogen ligand, and compound 2 is the first three-dimensional structure of a (five-coordinated) tetrahydrofurfurylcobalt(III) complex. Grid-search and Rietveld refinement have been used to determine and refine the structures, respectively. Crystals of 1 are orthorhombic, space group Pbca, Z = 8, with cell parameters a = 21.729 (2), b = 27.376 (3), c = 11.580 (1) A. Crystals of 2 are monoclinic, space group P2(1)/n, Z = 4, a = 16.6701 (6), b = 9.4170 (4), c = 13.7088 (7) A and beta = 96.520 (3) degrees. Chemical diagrams for the two compounds are given. Soft restraints were applied during Rietveld refinement; for 1 converging to R(p) = 8.4%, R(w) = 11.0%, GoF = 2.3, and for 2 converging to R(p) = 8.5%, R(w) = 11.4%, GoF = 7.6
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|a Journal Article
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1 |
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|a Goubitz, K
|e verfasserin
|4 aut
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1 |
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|a van Langevelde, A
|e verfasserin
|4 aut
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|a Driessen, R
|e verfasserin
|4 aut
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|a Mahabiersing, T
|e verfasserin
|4 aut
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|a Blaauw, R
|e verfasserin
|4 aut
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|a Peschar, R
|e verfasserin
|4 aut
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|a Schenk, H
|e verfasserin
|4 aut
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|i Enthalten in
|t Journal of synchrotron radiation
|d 1999
|g 8(2001), Pt 6 vom: 01. Nov., Seite 1186-90
|w (DE-627)NLM09824129X
|x 0909-0495
|7 nnns
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|g volume:8
|g year:2001
|g number:Pt 6
|g day:01
|g month:11
|g pages:1186-90
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|a GBV_USEFLAG_A
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|a SYSFLAG_A
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|a GBV_NLM
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|a GBV_ILN_40
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|a GBV_ILN_350
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|a GBV_ILN_2005
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|a AR
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|d 8
|j 2001
|e Pt 6
|b 01
|c 11
|h 1186-90
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