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|a (DE-627)NLM114376816
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|a (NLM)11539837
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|a DE-627
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|a eng
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|a Hwang, H J
|e verfasserin
|4 aut
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|a Infrared laser spectroscopy of jet-cooled carbon clusters
|b structure of triplet C6
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|c 1993
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|a Text
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|2 rdacontent
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|a ohne Hilfsmittel zu benutzen
|b n
|2 rdamedia
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|a Band
|b nc
|2 rdacarrier
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|a Date Completed 07.09.1997
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|a Date Revised 19.11.2009
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|a published: Print
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|a Citation Status MEDLINE
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|a We report the first structural characterization of the triplet isomer of C6. Forty-one rovibrational/fine structure transitions in the nu 4(sigma u) antisymmetric stretch fundamental of the C6 cluster have been measured by diode laser absorption spectroscopy of a supersonic carbon cluster beam. The observed spectrum is characteristic of a centrosymmetric linear triplet state with cumulene-type bonding. The measured ground state rotational constant B0 = 0.048 479 (10)cm-1 and the effective bond length r(eff) = 1.2868 (1) angstroms are in good agreement with ab initio predictions for the linear triplet (3 sigma g-) state of C6
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|a Journal Article
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|a Research Support, U.S. Gov't, Non-P.H.S.
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|a NASA Discipline Exobiology
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|a Non-NASA Center
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|a Carbon
|2 NLM
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|a 7440-44-0
|2 NLM
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|a Van Orden, A
|e verfasserin
|4 aut
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|a Tanaka, K
|e verfasserin
|4 aut
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|a Kuo, E W
|e verfasserin
|4 aut
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|a Heath, J R
|e verfasserin
|4 aut
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|a Saykally, R J
|e verfasserin
|4 aut
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|a Saykally, R W
|e investigator
|4 oth
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| 773 |
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|i Enthalten in
|t Molecular physics
|d 1993
|g 79(1993), 4 vom: 28., Seite 769-76
|w (DE-627)NLM098122959
|x 0026-8976
|7 nnns
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| 773 |
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|g volume:79
|g year:1993
|g number:4
|g day:28
|g pages:769-76
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|a GBV_USEFLAG_A
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|a SYSFLAG_A
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|a GBV_ILN_350
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|a AR
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|d 79
|j 1993
|e 4
|b 28
|h 769-76
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