Determination of the iron oxidation state in earth materials using XANES pre-edge information

Fe K-edge XANES spectra have been measured in more than 35 Fe(II) and Fe(III)-bearing minerals. The separation between the average pre-edge centroid positions for Fe(II) and Fe(III) is 1.4 +/- 0.1 eV. Examination of calculated pre-edge features of mechanical mixtures of phases containing different p...

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Veröffentlicht in:Journal of synchrotron radiation. - 1994. - 8(2001), Pt 2 vom: 01. März, Seite 952-4
1. Verfasser: Petit, P E (VerfasserIn)
Weitere Verfasser: Farges, F, Wilke, M, Solé, V A
Format: Aufsatz
Sprache:English
Veröffentlicht: 2001
Zugriff auf das übergeordnete Werk:Journal of synchrotron radiation
Schlagworte:Journal Article
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520 |a Fe K-edge XANES spectra have been measured in more than 35 Fe(II) and Fe(III)-bearing minerals. The separation between the average pre-edge centroid positions for Fe(II) and Fe(III) is 1.4 +/- 0.1 eV. Examination of calculated pre-edge features of mechanical mixtures of phases containing different proportions of Fe(II) and Fe(III) reveals that different trends of pre-edge position vs. pre-edge intensity can be observed, depending on the coordination environment. Both pre-edge parameters have been used to estimate the ferric/ferrous ratio in 12 natural minerals 
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700 1 |a Wilke, M  |e verfasserin  |4 aut 
700 1 |a Solé, V A  |e verfasserin  |4 aut 
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