Soft x-ray absorption spectra of ilmenite family

We have carried out soft x-ray absorption spectroscopy to study the electronic structure of ilmenite family, such as MnTiO3, FeTiO3, and CoTiO3 at the soft x-ray beamline, BL23SU, at the SPring-8. The Ti and M L2,3 absorption spectra of MTiO3 (M=Mn, Fe, and Co) show spectra of Ti4+ and M2+ electron...

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Veröffentlicht in:Journal of synchrotron radiation. - 1994. - 8(2001), Pt 2 vom: 01. März, Seite 907-9
1. Verfasser: Agui, A (VerfasserIn)
Weitere Verfasser: Mizumaki, M, Saitoh, Y, Matsushita, T, Nakatani, T, Fukaya, A, Torikai, E
Format: Aufsatz
Sprache:English
Veröffentlicht: 2001
Zugriff auf das übergeordnete Werk:Journal of synchrotron radiation
Schlagworte:Journal Article
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520 |a We have carried out soft x-ray absorption spectroscopy to study the electronic structure of ilmenite family, such as MnTiO3, FeTiO3, and CoTiO3 at the soft x-ray beamline, BL23SU, at the SPring-8. The Ti and M L2,3 absorption spectra of MTiO3 (M=Mn, Fe, and Co) show spectra of Ti4+ and M2+ electron configurations, respectively. Except the Fe L2,3 spectrum, those spectra were understood within the O(h) symmetry around the transition metal ions. The Fe L3-edge spectrum clearly shows a doublet peak at the L3 edge, which is attributed to Fe2+ state, moreover the very high-resolution the L-edge spectra of transition metals show fine structures. The spectra of those ilmenites are compared 
650 4 |a Journal Article 
700 1 |a Mizumaki, M  |e verfasserin  |4 aut 
700 1 |a Saitoh, Y  |e verfasserin  |4 aut 
700 1 |a Matsushita, T  |e verfasserin  |4 aut 
700 1 |a Nakatani, T  |e verfasserin  |4 aut 
700 1 |a Fukaya, A  |e verfasserin  |4 aut 
700 1 |a Torikai, E  |e verfasserin  |4 aut 
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