Studies on the heme and H2-uptake reaction from Azotobacter vinelandii bacterial ferritin

Bacterial ferritin of Azotobacter vinelandii (AvBF) is directly able to pick electrons up for iron release from or transfer them for storage to a platinum electrode in the absence of mediator or other reducer. The ferritin containing the structure of heme-Co2+ in part shows weakened activity to elec...

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Veröffentlicht in:Bioelectrochemistry and bioenergetics (Lausanne, Switzerland). - 1999. - 48(1999), 1 vom: 03. Feb., Seite 87-93
1. Verfasser: Huang, H Q (VerfasserIn)
Weitere Verfasser: Lin, Q M, Zhang, F Z, Chen, C H, Chen, X, Chen, Z
Format: Aufsatz
Sprache:English
Veröffentlicht: 1999
Zugriff auf das übergeordnete Werk:Bioelectrochemistry and bioenergetics (Lausanne, Switzerland)
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Heme 42VZT0U6YR Hydrogen 7YNJ3PO35Z Ferritins 9007-73-2 Iron E1UOL152H7 mehr... Oxygen S88TT14065
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245 1 0 |a Studies on the heme and H2-uptake reaction from Azotobacter vinelandii bacterial ferritin 
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520 |a Bacterial ferritin of Azotobacter vinelandii (AvBF) is directly able to pick electrons up for iron release from or transfer them for storage to a platinum electrode in the absence of mediator or other reducer. The ferritin containing the structure of heme-Co2+ in part shows weakened activity to electrode and decreases the rate of iron release greatly. A reversible reduction process of the ferritin is observed by the spectral change regularly ranging from 310 to 260 nm under mixed gases containing 98% H2 and 2% to O2. The activity of nitrogen fixation from the whole cell of A. vinelandii increases greatly by H2 reduction with potentials ranging from -397 to -425 mV vs. NHE, indicating two important roles of H2-uptake reaction of the ferritin in increasing activity of nitrogen fixation and in supplying iron to synthesize nitrogenase 
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650 4 |a Research Support, Non-U.S. Gov't 
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700 1 |a Lin, Q M  |e verfasserin  |4 aut 
700 1 |a Zhang, F Z  |e verfasserin  |4 aut 
700 1 |a Chen, C H  |e verfasserin  |4 aut 
700 1 |a Chen, X  |e verfasserin  |4 aut 
700 1 |a Chen, Z  |e verfasserin  |4 aut 
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