Coastal ocean and shelf-sea biogeochemical cycling of trace elements and isotopes: lessons learned from GEOTRACES

Continental shelves and shelf seas play a central role in the global carbon cycle. However, their importance with respect to trace element and isotope (TEI) inputs to ocean basins is less well understood. Here, we present major findings on shelf TEI biogeochemistry from the GEOTRACES programme as we...

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Veröffentlicht in:Philosophical Transactions: Mathematical, Physical and Engineering Sciences. - The Royal Society. - 374(2016), 2081, Seite 1-19
1. Verfasser: Charette, Matthew A. (VerfasserIn)
Weitere Verfasser: Lam, Phoebe J., Lohan, Maeve C., Kwon, Eun Young, Hatje, Vanessa, Jeandel, Catherine, Shiller, Alan M., Cutter, Gregory A., Thomas, Alex, Boyd, Philip W., Homoky, William B., Milne, Angela, Thomas, Helmuth, Andersson, Per S., Porcelli, Don, Tanaka, Takahiro, Geibert, Walter, Dehairs, Frank, Garcia-Orellana, Jordi
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2016
Zugriff auf das übergeordnete Werk:Philosophical Transactions: Mathematical, Physical and Engineering Sciences
Schlagworte:Physical sciences Business Biological sciences
Beschreibung
Zusammenfassung:Continental shelves and shelf seas play a central role in the global carbon cycle. However, their importance with respect to trace element and isotope (TEI) inputs to ocean basins is less well understood. Here, we present major findings on shelf TEI biogeochemistry from the GEOTRACES programme as well as a proof of concept for a new method to estimate shelf TEI fluxes. The case studies focus on advances in our understanding of TEI cycling in the Arctic, transformations within a major river estuary (Amazon), shelf sediment micronutrient fluxes and basin-scale estimates of submarine groundwater discharge. The proposed shelf flux tracer is 228-radium (T½ = 5.75 yr), which is continuously supplied to te shelf from coastal aquifers, sediment porewater exchange and rivers. Model-derived shelf ²²⁸Ra fluxes are combined with TEI/ ²²⁸Ra ratios to quantify ocean TEI fluxes from the western North Atlantic margin. The results from this new approach agree well with previous estimates for shelf Co, Fe, Mn and Zn inputs and exceed published estimates of atmospheric deposition by factors of approximately 3–23. Lastly, recommendations are made for additional GEOTRACES process studies and coastal margin-focused section cruises that will help refine the model and provide better insight on the mechanisms driving self-derived TEI fluxes to the ocean. This article is part of the themed issue 'Biological and climatic impacts of ocean trace element chemistry'.
ISSN:1364503X