Electric-Field Regulation of Adhesion/De-Adhesion/Release Capacity of Transparent and Electrochromic Adhesive

© 2025 Wiley‐VCH GmbH.

Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Deerfield Beach, Fla.). - 1998. - (2025) vom: 08. Apr., Seite e2500648
1. Verfasser: Yao, Guohong (VerfasserIn)
Weitere Verfasser: Gao, Miaomiao, Zhang, Qiao, Tan, Xin, Cai, Changyong, Dong, Shengyi
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2025
Zugriff auf das übergeordnete Werk:Advanced materials (Deerfield Beach, Fla.)
Schlagworte:Journal Article electric regulation electric release electrochromism supramolecular adhesion transparent adhesive
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520 |a Removing adhesive nondestructively and intact from the adhered surface is a difficult challenge for advanced adhesive materials. Compared with the commonly used thermal or chemical release, the controlled adhesive release via electric-field offers practical application advantages. However, a noninvasive release mode such as this has not been available for the de-bonding of supramolecular adhesives that originate from small organic molecules. Herein, a conductive hydrogel with surface adhesion and electric field-triggered de-adhesion and release is fabricated from thioctic acid (TA) and L-arginine (LA). The non-covalent intermolecular attractions of poly[TA-LA], especially its electrostatic interactions, not only endow it with useful bulk-state properties and strong adhesion (up to 363.3 kPa) but also generate electric responsiveness for on-demand de-adhesion and release. The poly[TA-LA] adhesive layer can be easily released within a short time (<60 s) under a mild voltage (5≈10 V). After a combined experimental and theoretical investigation, It is concluded that the adhesive-layer morphological and mechanical changes, activated by a weak current (1.1≈3.2 mA), are responsible for the adhesion failure, which takes place primarily at the anode. Importantly, rapid electric release of poly[TA-LA] is applicable at low temperatures (5 V, 60 s, -40 °C) or underwater (5 V, 60 s, 25 °C) 
650 4 |a Journal Article 
650 4 |a electric regulation 
650 4 |a electric release 
650 4 |a electrochromism 
650 4 |a supramolecular adhesion 
650 4 |a transparent adhesive 
700 1 |a Gao, Miaomiao  |e verfasserin  |4 aut 
700 1 |a Zhang, Qiao  |e verfasserin  |4 aut 
700 1 |a Tan, Xin  |e verfasserin  |4 aut 
700 1 |a Cai, Changyong  |e verfasserin  |4 aut 
700 1 |a Dong, Shengyi  |e verfasserin  |4 aut 
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