A High-Rate and Ultrastable Ammonium Ion-Air Battery Enabled by the Synergy of ORR and NH4 + Storage
© 2025 Wiley‐VCH GmbH.
| Publié dans: | Advanced materials (Deerfield Beach, Fla.). - 1998. - 37(2025), 19 vom: 27. Mai, Seite e2415476 |
|---|---|
| Auteur principal: | |
| Autres auteurs: | , , , , , , |
| Format: | Article en ligne |
| Langue: | English |
| Publié: |
2025
|
| Accès à la collection: | Advanced materials (Deerfield Beach, Fla.) |
| Sujets: | Journal Article air cathode ammonium ion batteries neutral electrolyte oxygen reduction reaction |
| Résumé: | © 2025 Wiley‐VCH GmbH. Ammonium ion batteries (AIBs) offer cost-effectiveness, nontoxicity, and eco-friendly attributes in energy storage technology. However, the constrained capacity and poor stability of conventional cathode materials have impeded their widespread adoption. Herein, a synergistic approach is introduced to overcome these challenges, by enhancing the air cathode with NH4 + and simultaneously leveraging atmospheric oxygen as a reservoir for NH4 + storage. Notably, NH4 + significantly enhances the oxygen reduction reaction (ORR) performance in neutral environments. Through in situ Raman spectroscopy and quantum density functional theory calculations, it is elucidated how NH4 + can act as a proton donor, replacing H2O in neutral media and reducing energy barriers in the protonation of *O2 - and *O, thereby accelerating ORR kinetics. The resulting ammonium ion-air battery, comprising an air cathode and a polymer (PNP) anode, showcases impressive metrics: high energy density of 78 Wh kg-1 and power density of 9369 W kg-1 at 1 A g-1, an initial capacity of 94.3 mAh g-1 and exceptional cycling stability (70.4% capacity retention after 12 500 cycles) at 10 A g-1. This pioneering research highlights the synergistic relationship between ORR and NH4 + storage and opens up new avenues for the design and advancement of innovative, sustainable, and environment-friendly AIBs |
|---|---|
| Description: | Date Revised 14.05.2025 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 1521-4095 |
| DOI: | 10.1002/adma.202415476 |