Diesel removal in non-aqueous phase by fibres from Calotropis procera : kinetic, isothermal and sorption potential evaluation

Calotropis procera fibres have been proposed for free-phase diesel removal in case of spillage into groundwater. For this, characterizations were carried out using Fourier transform infrared spectroscopy (FTIR), field emission scanning electron microscopy (FEG-SEM), wettability and contact angle mea...

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Publié dans:Environmental technology. - 1993. - 46(2025), 7 vom: 14. März, Seite 1005-1020
Auteur principal: de França, Maíra Rachel Gerônimo (Auteur)
Autres auteurs: Anjos, Raoni Batista Dos, Hilário, Larissa Sobral, Oliveira, Ingrid de Castro Dos Santos, Silva, Augusto Manoel Araújo, Gondim, Ysla Karoline Ferreira, Martínez-Huitle, Carlos Alberto, Gondim, Amanda Duarte
Format: Article en ligne
Langue:English
Publié: 2025
Accès à la collection:Environmental technology
Sujets:Journal Article Fibre Calotropis procera diesel kinetic-isothermal light non-aqueous phase liquid sorption Gasoline Water Pollutants, Chemical
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520 |a Calotropis procera fibres have been proposed for free-phase diesel removal in case of spillage into groundwater. For this, characterizations were carried out using Fourier transform infrared spectroscopy (FTIR), field emission scanning electron microscopy (FEG-SEM), wettability and contact angle measurements. Sorption oil capacity, kinetic, isothermal and recycling behaviour were evaluated. For initial optimization of the oil sorption capacity, an experimental design (DOE) was applied, with the optimized condition being 60 g L-1 of diesel in water and 0.01 g of fibre. Then, the results clearly indicated that the fibres have a hydrophobic and oleophilic character, quickly reaching more than 71.43 g g-1 of diesel sorption, according to the adjustment (R² > 0.99) of the pseudo-second order and Langmuir models, governed by absorption mechanisms. It should also be noted that at the end of 8 reuse cycles, the fibre presented a total accumulated sorption capacity of about 252.6 g g-1 of diesel. Furthermore, a laboratory-scale experiment was carried out to remove diesel from groundwater in gas station areas, the fibre removed 98.55% to 99.97% of removal efficiencies were achieved of the free phase over time. Therefore, the material demonstrates excellent characteristics for removing diesel spills in groundwater due to its fast, high and stable removal capacity 
650 4 |a Journal Article 
650 4 |a Fibre Calotropis procera 
650 4 |a diesel 
650 4 |a kinetic-isothermal 
650 4 |a light non-aqueous phase liquid 
650 4 |a sorption 
650 7 |a Gasoline  |2 NLM 
650 7 |a Water Pollutants, Chemical  |2 NLM 
700 1 |a Anjos, Raoni Batista Dos  |e verfasserin  |4 aut 
700 1 |a Hilário, Larissa Sobral  |e verfasserin  |4 aut 
700 1 |a Oliveira, Ingrid de Castro Dos Santos  |e verfasserin  |4 aut 
700 1 |a Silva, Augusto Manoel Araújo  |e verfasserin  |4 aut 
700 1 |a Gondim, Ysla Karoline Ferreira  |e verfasserin  |4 aut 
700 1 |a Martínez-Huitle, Carlos Alberto  |e verfasserin  |4 aut 
700 1 |a Gondim, Amanda Duarte  |e verfasserin  |4 aut 
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773 1 8 |g volume:46  |g year:2025  |g number:7  |g day:14  |g month:03  |g pages:1005-1020 
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