Effect of polyethylene terephthalate plastics on nitrogen, sulphur and chlorine contaminants via sludge pyrolysis and Pb/Cu adsorption properties of biochar

Pyrolysis is an effective process for disposing of municipal sewage sludge (SS). Plastics can affect the SS pyrolysis behaviour and pyrolysis products due to their low ash and high hydrocarbon ratio. The secondary pollutants from the pyrolysis process may also be affected. Therefore, polyethylene te...

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Détails bibliographiques
Publié dans:Environmental technology. - 1993. - 46(2025), 6 vom: 21. Feb., Seite 895-907
Auteur principal: Li, Yurong (Auteur)
Autres auteurs: Fu, Chuan, Xia, Yaping, Wu, Yan, Hu, Kewei, Shen, Jia, Zhu, Yin, Peng, Hanyu, Wang, Dan, Yan, Jingsong
Format: Article en ligne
Langue:English
Publié: 2025
Accès à la collection:Environmental technology
Sujets:Journal Article PET plastics Sewage sludge heavy metal adsorption properties pollutant release characteristics three-phase products Polyethylene Terephthalates biochar Charcoal 16291-96-6 plus... Sewage Sulfur 70FD1KFU70 Lead 2P299V784P Copper 789U1901C5 Nitrogen N762921K75 Chlorine 4R7X1O2820
Description
Résumé:Pyrolysis is an effective process for disposing of municipal sewage sludge (SS). Plastics can affect the SS pyrolysis behaviour and pyrolysis products due to their low ash and high hydrocarbon ratio. The secondary pollutants from the pyrolysis process may also be affected. Therefore, polyethylene terephthalate (PET), a typical plastic, was chosen to investigate the release characteristics of pollutants containing nitrogen, sulphur, and chlorine via SS pyrolysis, and the changes of biochar to adsorb two typical heavy metals, Pb and Cu. The pyrolysis of PET plastics facilitates the migration of N toward solid and liquid-phase products, S and Cl to the gas-phase products via pyrolysis. Oxygenated compounds of pyrolytic volatiles decreased from 38.18% to 28.43%, concurrently promoting the formation of phenolic compounds. The co-pyrolysis improved the quality of biochar and the ability to adsorb Pb and Cu. This systematic study can provide some support for the further improvement of SS pyrolysis technology, and will also be beneficial for subsequent applications
Description:Date Completed 22.04.2025
Date Revised 22.04.2025
published: Print-Electronic
Citation Status MEDLINE
ISSN:1479-487X
DOI:10.1080/09593330.2024.2371079