|
|
|
|
| LEADER |
01000caa a22002652 4500 |
| 001 |
NLM372454143 |
| 003 |
DE-627 |
| 005 |
20240518232720.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
240517s2024 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1021/acs.organomet.4c00108
|2 doi
|
| 028 |
5 |
2 |
|a pubmed24n1411.xml
|
| 035 |
|
|
|a (DE-627)NLM372454143
|
| 035 |
|
|
|a (NLM)38756990
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Dabbs, Jonathan D
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a Synthesis of 1-Azatriene Complexes of Tungsten
|b Metal-Promoted Ring-Opening of Dihydropyridine
|
| 264 |
|
1 |
|c 2024
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Revised 18.05.2024
|
| 500 |
|
|
|a published: Electronic-eCollection
|
| 500 |
|
|
|a Citation Status PubMed-not-MEDLINE
|
| 520 |
|
|
|a © 2024 The Authors. Published by American Chemical Society.
|
| 520 |
|
|
|a For nearly a century, chemists have explored how transition-metal complexes can affect the physical and chemical properties of linear conjugated polyenes and heteropolyenes. While much has been written about higher hapticity complexes (η4-η6), less is known about the chemistry of their η2 analogues. Herein, we describe a general method for synthesizing 5,6-η2-(1-azatriene) tungsten complexes via a 6π-azaelectrocyclic dihydropyridine ring-opening that is promoted by the π-basic nature of {WTp(NO)(PMe3)}. This study includes detailed spectroscopic and crystallographic data for the η2-dihydropyridine and η2-1-azatriene complexes, both of which were prepared as single regio- and stereoisomers
|
| 650 |
|
4 |
|a Journal Article
|
| 700 |
1 |
|
|a Ericson, Megan N
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Dickie, Diane A
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Harman, W Dean
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Organometallics
|d 1998
|g 43(2024), 9 vom: 13. Mai, Seite 1051-1056
|w (DE-627)NLM098167103
|x 0276-7333
|7 nnns
|
| 773 |
1 |
8 |
|g volume:43
|g year:2024
|g number:9
|g day:13
|g month:05
|g pages:1051-1056
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1021/acs.organomet.4c00108
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_350
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 43
|j 2024
|e 9
|b 13
|c 05
|h 1051-1056
|