|
|
|
|
| LEADER |
01000caa a22002652 4500 |
| 001 |
NLM369067061 |
| 003 |
DE-627 |
| 005 |
20240312234014.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
240229s2024 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1021/acs.langmuir.4c00078
|2 doi
|
| 028 |
5 |
2 |
|a pubmed24n1324.xml
|
| 035 |
|
|
|a (DE-627)NLM369067061
|
| 035 |
|
|
|a (NLM)38416792
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Zhang, Xupeng
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a Innovative Catalyst Design of Sea-Urchin-like NiCoP Nanoneedle Arrays Supported on N-Doped Carbon Nanospheres for Enhanced HER Performance
|
| 264 |
|
1 |
|c 2024
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Revised 12.03.2024
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status PubMed-not-MEDLINE
|
| 520 |
|
|
|a Hydrogen (H2) stands as a clean energy alternative to fossil fuels, especially within the domain of the hydrogen evolution reaction (HER), offering prospective solutions to mitigate both environmental and energy-related challenges. In this work, we successfully synthesized a sea-urchin-like catalyst, specifically a nickel-cobalt phosphide nanoneedle array on N-doped carbon nanospheres (Ni0.5Co1.5PNCSs), for efficient HER by a sequential hydrothermal and low-temperature phosphating process. The catalyst exhibits sea-urchin-like structures, offering a specific surface area of 298 m2 g-1 and consequently furnishing a greater abundance of active sites. Comparing with non-sea-urchin-like Ni0.5Co1.5P@CN catalysts, the Ni0.5Co1.5P@NCSs exhibit an overpotential of 163 mV at 10 mA cm-2, a Tafel slope of 60 mV dec-1, and a maintained current density of approximately 90% during 50 h of continuous electrolysis. Experiments demonstrate that the outstanding electrochemical properties of the Ni0.5Co1.5P@NCSs originate from nitrogen doping of carbon spheres, the distinctive morphology of sea-urchin-like nanoneedle arrays, and simultaneous enhancements in intermediate adsorption energy, charge transfer, and electrolyte diffusion channel shortening. This work emphasizes a preparation strategy for synthesizing an attractive electrocatalyst with a low cost and efficient HER performance
|
| 650 |
|
4 |
|a Journal Article
|
| 700 |
1 |
|
|a Wang, Jiabo
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Bi, Yiyang
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Wang, Ying
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Liu, Qun
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Zhang, Yu
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Chen, Li
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 40(2024), 10 vom: 12. März, Seite 5518-5526
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
|
| 773 |
1 |
8 |
|g volume:40
|g year:2024
|g number:10
|g day:12
|g month:03
|g pages:5518-5526
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1021/acs.langmuir.4c00078
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_22
|
| 912 |
|
|
|a GBV_ILN_350
|
| 912 |
|
|
|a GBV_ILN_721
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 40
|j 2024
|e 10
|b 12
|c 03
|h 5518-5526
|