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231226s2023 xx |||||o 00| ||eng c |
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|a 10.1002/adma.202301538
|2 doi
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|a pubmed24n1234.xml
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|a DE-627
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|a eng
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|a Du, Kai
|e verfasserin
|4 aut
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|a High Entropy Oxides Modulate Atomic-Level Interactions for High-Performance Aqueous Zinc-Ion Batteries
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|c 2023
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|a Text
|b txt
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
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|2 rdacarrier
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|a Date Revised 21.12.2023
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a © 2023 Wiley-VCH GmbH.
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|a The strong electrostatic interaction between high-charge-density zinc ions (112 C mm-3 ) and the fixed crystallinity of traditional oxide cathodes with delayed charge compensation hinders the development of high-performance aqueous zinc-ion batteries (AZIBs). Herein, to intrinsically promote electron transfer efficiency and improve lattice tolerance, a revolutionary family of high-entropy oxides (HEOs) materials with multipath electron transfer and remarkable structural stability as cathodes for AZIBs is proposed. Benefiting from the unique "cock-tail" effect, the interaction of diverse type metal-atoms in HEOs achieves essentially broadened d-band and lower degeneracy than monometallic oxides, which contribute to convenient electron transfer and one of the best rate-performances (136.2 mAh g-1 at 10.0 A g-1 ) in AZIBs. In addition, the intense lattice strain field of HEOs is highly tolerant to the electrostatic repulsion of high-charge-density Zn2+ , leading to the outstanding cycling stability in AZIBs. Moreover, the super selectability of elements in HEOs exhibits significant potential for AZIBs
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|a Journal Article
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|a aqueous zinc-ion batteries
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|a high charge density
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|a high entropy
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|a high rate performance
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|a modulated d-band
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|a Liu, Yujie
|e verfasserin
|4 aut
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|a Yang, Yunfei
|e verfasserin
|4 aut
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|a Cui, Fangyan
|e verfasserin
|4 aut
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|a Wang, Jinshu
|e verfasserin
|4 aut
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|a Han, Mingshan
|e verfasserin
|4 aut
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|a Su, Jingwen
|e verfasserin
|4 aut
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|a Wang, Jiajun
|e verfasserin
|4 aut
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|a Han, Xiaopeng
|e verfasserin
|4 aut
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|a Hu, Yuxiang
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 35(2023), 51 vom: 25. Dez., Seite e2301538
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
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| 773 |
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|g volume:35
|g year:2023
|g number:51
|g day:25
|g month:12
|g pages:e2301538
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|u http://dx.doi.org/10.1002/adma.202301538
|3 Volltext
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