Preparation of CoFe2O4-Doped TiO2 Nanofibers by Electrospinning and Annealing for Oxygen Electrocatalysis

In this paper, catalyst precursor fibers were prepared by a sol gel method combined with an electrospinning method using tetrabutyl titanate as a titanium source, cobalt acetylacetonate as a cobalt source, and iron acetylacetonate as an iron source. CoFeTiO2 nanofibers (NFs) with a bimetallic spinel...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1985. - 39(2023), 17 vom: 02. Mai, Seite 6211-6221
1. Verfasser: Xu, Xiaoting (VerfasserIn)
Weitere Verfasser: Xi, Ruifan, Li, Yuanyuan, Wang, Ping, Zhang, Yan, Hu, Dongmei
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2023
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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245 1 0 |a Preparation of CoFe2O4-Doped TiO2 Nanofibers by Electrospinning and Annealing for Oxygen Electrocatalysis 
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520 |a In this paper, catalyst precursor fibers were prepared by a sol gel method combined with an electrospinning method using tetrabutyl titanate as a titanium source, cobalt acetylacetonate as a cobalt source, and iron acetylacetonate as an iron source. CoFeTiO2 nanofibers (NFs) with a bimetallic spinel structure were formed after thermal annealing, which have dual-functional catalytic activity. With the molar ratio of Co and Fe coming to 1:1, a typical spinel CoFe2O4 structure was generated in Co1Fe1@TiO2 NFs. At a load of only 28.7 μg·cm-2, Co1Fe1@TiO2 NFs not only have a low overpotential (284 mV) and Tafel slope (54 mV·dec-1) in the oxygen evolution reaction but also show a high initial potential (0.88 V) and limiting current density (6.40 mA·cm-2) in the oxygen reduction reaction. Meanwhile, Co1Fe1@TiO2 NFs exhibit good durability, cycle stability, and dual-function catalysis 
650 4 |a Journal Article 
700 1 |a Xi, Ruifan  |e verfasserin  |4 aut 
700 1 |a Li, Yuanyuan  |e verfasserin  |4 aut 
700 1 |a Wang, Ping  |e verfasserin  |4 aut 
700 1 |a Zhang, Yan  |e verfasserin  |4 aut 
700 1 |a Hu, Dongmei  |e verfasserin  |4 aut 
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