Critical Amphiphilic Concentration : Effect of the Extent of Amphiphilicity on Marine Fouling-Release Performance

Amphiphilic surfaces, containing both hydrophilic and hydrophobic domains, offer desirable performance for many applications such as marine coatings or anti-icing purposes. This work explores the effect of the concentration of amphiphilic moieties on converting a polyurethane (PU) system to a coatin...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1985. - 37(2021), 8 vom: 02. März, Seite 2728-2739
1. Verfasser: Rahimi, AliReza (VerfasserIn)
Weitere Verfasser: Stafslien, Shane J, Vanderwal, Lyndsi, Bahr, James, Safaripour, Maryam, Finlay, John A, Clare, Anthony S, Webster, Dean C
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2021
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, U.S. Gov't, P.H.S.
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520 |a Amphiphilic surfaces, containing both hydrophilic and hydrophobic domains, offer desirable performance for many applications such as marine coatings or anti-icing purposes. This work explores the effect of the concentration of amphiphilic moieties on converting a polyurethane (PU) system to a coating having fouling-release properties. A novel amphiphilic compound is synthesized and added at increasing amounts to a PU system, where the amount of the additive is the only variable in the study. The additive-modified surfaces are characterized by a variety of techniques including ATR-FTIR, XPS, contact angle measurements, and AFM. Surface characterizations indicate the presence of amphiphilic domains on the surface due to the introduction of the self-stratifying amphiphilic additive. The fouling-release properties of the surfaces are assessed with three biological assays using Ulva linza, Cellulophaga lytica, and Navicula Incerta as the test organisms. A change in the fouling-release performance is observed and plateaued once a certain amount of amphiphilicity is attained in the coating system, which we call the critical amphiphilic concentration (CAC) 
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650 4 |a Research Support, U.S. Gov't, P.H.S. 
700 1 |a Stafslien, Shane J  |e verfasserin  |4 aut 
700 1 |a Vanderwal, Lyndsi  |e verfasserin  |4 aut 
700 1 |a Bahr, James  |e verfasserin  |4 aut 
700 1 |a Safaripour, Maryam  |e verfasserin  |4 aut 
700 1 |a Finlay, John A  |e verfasserin  |4 aut 
700 1 |a Clare, Anthony S  |e verfasserin  |4 aut 
700 1 |a Webster, Dean C  |e verfasserin  |4 aut 
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