Micellar Lyotropic Nematic Gels
© 2021 The Authors. Advanced Materials published by Wiley-VCH GmbH.
| Publié dans: | Advanced materials (Deerfield Beach, Fla.). - 1998. - 33(2021), 8 vom: 26. Feb., Seite e2007340 |
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| Auteur principal: | |
| Autres auteurs: | , , |
| Format: | Article en ligne |
| Langue: | English |
| Publié: |
2021
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| Accès à la collection: | Advanced materials (Deerfield Beach, Fla.) |
| Sujets: | Journal Article low-molecular-weight gelators lyotropic liquid crystals lyotropic nematic gels self-assembled fibrillar networks |
| Résumé: | © 2021 The Authors. Advanced Materials published by Wiley-VCH GmbH. Lyotropic liquid crystal (LLC) gels are a new class of liquid crystal (LC) networks that combine the anisotropy of micellar LLCs with the mechanical stability of a gel. However, so far, only micellar LLC gels with lamellar and hexagonal structures have been obtained by the addition of gelators to LLCs. Here, the first examples of lyotropic nematic gels are presented. The key to obtain these nematic gels is the use of gelators that have a non-amphiphilic molecular structure and thus leave the size and shape of the micellar aggregates essentially unchanged. By adding these gelators to lyotropic nematic phases, an easy and reproducible way to obtain large amounts of lyotropic nematic gels is established. These nematic gels preserve the long-range orientational order and optical birefringence of a lyotropic nematic phase but have the mechanical stability of a gel. LLC nematic gels are promising new materials for elastic and anisotropic hydrogels to be applied as water-based stimuli-responsive actuators and sensors |
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| Description: | Date Revised 13.10.2024 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 1521-4095 |
| DOI: | 10.1002/adma.202007340 |