Nitrogen-doped mesoporous carbon material (NCMK-3) as a catalyst for the removal of 4-chlorophenol during persulfate oxidation and its efficiency after reuse

Persulfate (PS) oxidation of 4-chlorophenol (4CP) is mostly catalysed by relatively expensive metal substrates. In this study, we investigated the influence of nitrogen-doped and non-doped mesoporous carbon materials (NCMK-3 and CMK-3) during persulfate (PS) oxidation of 4CP in water. Batch experime...

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Veröffentlicht in:Environmental technology. - 1993. - 43(2022), 2 vom: 28. Jan., Seite 192-198
1. Verfasser: Addison, Francis (VerfasserIn)
Weitere Verfasser: Offiong, Nnanake-Abasi, Han, Qilin, Wang, Ruofan, Liu, Na
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2022
Zugriff auf das übergeordnete Werk:Environmental technology
Schlagworte:Journal Article 4-chlorophenol Mesoporous carbon material N-doped catalysis persulfate oxidation Chlorophenols Water Pollutants, Chemical 3DLC36A01X Carbon mehr... 7440-44-0 Nitrogen N762921K75
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520 |a Persulfate (PS) oxidation of 4-chlorophenol (4CP) is mostly catalysed by relatively expensive metal substrates. In this study, we investigated the influence of nitrogen-doped and non-doped mesoporous carbon materials (NCMK-3 and CMK-3) during persulfate (PS) oxidation of 4CP in water. Batch experiments were conducted such that PS was added to simulated contaminant mixture after 1 h agitation with NCMK-3 and CMK-3. Further, the experiment was carried out at different temperatures, pH ranges, concentrations of persulfate (PS), and different doses of NCMK-3, since it recorded better removal rates compared to CMK-3. The results revealed that NCMK-3 and CMK-3 aided the removal of 4CP from water during persulfate oxidation. When persulfate was added after an hour of equilibration with CMK-3 and NCMK-3, 83% and 92% of 4CP were removed within 20 min, respectively, whereas lower removal rates (≤40) were recorded in the absence of persulfate (PS). The removal rates of 4CP increased with an increase in temperature but reduced in the alkaline medium in the NCMK-3/PS system. The efficiency of the NCMK-3 reduced significantly after it was reused three times. Based on the results, NCMK-3 influences the activity of PS oxidation of 4-chlorophenol (4CP) and exhibited a synergistic effect in the removal of the organic contaminant from water 
650 4 |a Journal Article 
650 4 |a 4-chlorophenol 
650 4 |a Mesoporous carbon material 
650 4 |a N-doped 
650 4 |a catalysis 
650 4 |a persulfate oxidation 
650 7 |a Chlorophenols  |2 NLM 
650 7 |a Water Pollutants, Chemical  |2 NLM 
650 7 |a 4-chlorophenol  |2 NLM 
650 7 |a 3DLC36A01X  |2 NLM 
650 7 |a Carbon  |2 NLM 
650 7 |a 7440-44-0  |2 NLM 
650 7 |a Nitrogen  |2 NLM 
650 7 |a N762921K75  |2 NLM 
700 1 |a Offiong, Nnanake-Abasi  |e verfasserin  |4 aut 
700 1 |a Han, Qilin  |e verfasserin  |4 aut 
700 1 |a Wang, Ruofan  |e verfasserin  |4 aut 
700 1 |a Liu, Na  |e verfasserin  |4 aut 
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