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231225s2020 xx |||||o 00| ||eng c |
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|a 10.1021/acs.langmuir.0c00861
|2 doi
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|a eng
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| 100 |
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|a Fujii, Shota
|e verfasserin
|4 aut
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|a Structural Polymorphism of Resorcinarene Assemblies
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|c 2020
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
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|2 rdamedia
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|a ƒa Online-Ressource
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| 500 |
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|a Date Revised 09.06.2020
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a In 1997, a study based on X-ray crystallography revealed that resorcinarenes adopt a hexameric capsule-like structure. The function of resorcinarenes has been discussed on the basis of this structure; however, our recent study showed that the hexamer may be only one of resorcinarenes' polymorphic members. Here, we present the solvent dependence of the aggregation number of C-undecylresorcinarene in water-saturated toluene and chloroform using small-angle neutron and X-ray scattering and analytical ultracentrifugation measurements. We found that a new octamer was formed in toluene where the eight resorcinarene units were placed at the vertices of a regular cube; this contrasts to the previous structure in chloroform, namely, a hexamer with the six resorcinarenes located at the vertices of a regular octahedron that has a cavity inside where chloroform molecules are pooled
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|a Journal Article
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1 |
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|a Miyake, Rika
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Campo, Liliana de
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Lee, Ji Ha
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Takahashi, Rintaro
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Sakurai, Kazuo
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1985
|g 36(2020), 22 vom: 09. Juni, Seite 6222-6227
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnas
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| 773 |
1 |
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|g volume:36
|g year:2020
|g number:22
|g day:09
|g month:06
|g pages:6222-6227
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|u http://dx.doi.org/10.1021/acs.langmuir.0c00861
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