|
|
|
|
| LEADER |
01000caa a22002652 4500 |
| 001 |
NLM296823295 |
| 003 |
DE-627 |
| 005 |
20250225072149.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
231225s2019 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1002/adma.201901124
|2 doi
|
| 028 |
5 |
2 |
|a pubmed25n0989.xml
|
| 035 |
|
|
|a (DE-627)NLM296823295
|
| 035 |
|
|
|a (NLM)31062894
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Hu, Yating
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a Guided Assembly of Microporous/Mesoporous Manganese Phosphates by Bifunctional Organophosphonic Acid Etching and Templating
|
| 264 |
|
1 |
|c 2019
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Revised 30.09.2020
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status PubMed-not-MEDLINE
|
| 520 |
|
|
|a © 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
|
| 520 |
|
|
|a Manganese (Mn)-based compounds are important materials for both energy conversion and energy storage. Unfortunately, it has been a significant challenge to develop highly ordered microporous/mesoporous structures for them to provide more active sites for these applications. In order to do so using the soft-templating method, three conditions have to be met, namely, a strong interaction between the inorganic precursor and the organic templates; eliminating the formation of bulk manganese phosphate; and the preservation of the manganese phosphate framework without it collapsing upon template removal. Herein, a soft-templating approach is reported using an organophosphonic acid (n-hexylphosphonic acid) as both the etching and the templating agent, followed by high-vacuum-assisted annealing. This approach simultaneously satisfies the above conditions. Both microporous and mesoporous manganese phosphates with uniform pore sizes and well-defined pore structures are obtained. The utilization of the organophosphonic acid is shown to be the key in the transformation from bulk manganese oxide into a highly ordered microporous phosphate. A very high surface area of 304.1 m2 g-1 is obtained for the microporous manganese phosphate, which is the highest among the reported values for Mn-based compounds. The ultrafine micropores and high specific surface area of our manganese phosphate promote electrocatalytic activity for the oxygen evolution reaction
|
| 650 |
|
4 |
|a Journal Article
|
| 650 |
|
4 |
|a ionocovalent
|
| 650 |
|
4 |
|a manganese phosphate
|
| 650 |
|
4 |
|a microporous
|
| 650 |
|
4 |
|a oxygen evolution reaction
|
| 650 |
|
4 |
|a soft templates
|
| 700 |
1 |
|
|a Zhang, Yu
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Li, Changjian
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Wang, Ling
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Du, Yonghua
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Mo, Guang
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Li, Xu
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Cheetham, Anthony K
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Wang, John
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 31(2019), 25 vom: 26. Juni, Seite e1901124
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
|
| 773 |
1 |
8 |
|g volume:31
|g year:2019
|g number:25
|g day:26
|g month:06
|g pages:e1901124
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1002/adma.201901124
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_350
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 31
|j 2019
|e 25
|b 26
|c 06
|h e1901124
|