Adsorption of Cd2+ and Ni2+ from Aqueous Single-Metal Solutions on Graphene Oxide-Chitosan-Poly(vinyl alcohol) Hydrogels

The applications of graphene-based adsorbents were limited because of their complicated manufacturing technology and hi cost, thus it is very important to prepare new inexpensive and easily manufactured graphene-based adsorbents. Herein, novel GCP hydrogels with different graphene oxide (GO), chitos...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1985. - 35(2019), 13 vom: 02. Apr., Seite 4481-4490
1. Verfasser: Li, Chunya (VerfasserIn)
Weitere Verfasser: Yan, Yayuan, Zhang, Quanzhou, Zhang, Zhenbao, Huang, Langhuan, Zhang, Jingxian, Xiong, Yongqiang, Tan, Shaozao
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2019
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, Non-U.S. Gov't
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245 1 0 |a Adsorption of Cd2+ and Ni2+ from Aqueous Single-Metal Solutions on Graphene Oxide-Chitosan-Poly(vinyl alcohol) Hydrogels 
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500 |a Date Completed 25.06.2020 
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500 |a published: Print-Electronic 
500 |a ErratumIn: Langmuir. 2019 Jul 16;35(28):9323. doi: 10.1021/acs.langmuir.9b01659. - PMID 31276422 
500 |a Citation Status PubMed-not-MEDLINE 
520 |a The applications of graphene-based adsorbents were limited because of their complicated manufacturing technology and hi cost, thus it is very important to prepare new inexpensive and easily manufactured graphene-based adsorbents. Herein, novel GCP hydrogels with different graphene oxide (GO), chitosan (CS), and poly(vinyl alcohol) (PVA) ratios were facilely prepared through a method of freeze-thaw physical cross-linking, which was green and low-cost, and the structural characterization and adsorptive property of the optimum GCP1:2:4 hydrogel toward Cd2+ and Ni2+ in wastewater was evaluated. It was found that the GCP1:2:4 hydrogel had good mechanical strength and a special 3D interconnection porous structure. The isotherms of adsorption used the Langmuir model, and the kinetics of adsorption following the pseudo-second-order model were confirmed. Moreover, the adsorption property with respect to Cd2+ and Ni2+ in wastewater has been largely effected by the pH and was less influenced by the ionic strength and humic acid, and the GCP1:2:4 hydrogel possessed excellent adsorptive and recyclable properties. These results demonstrated that the GCP1:2:4 hydrogel could serve as a desirable adsorbent to get rid of heavy metal ions in sewage 
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650 4 |a Research Support, Non-U.S. Gov't 
700 1 |a Yan, Yayuan  |e verfasserin  |4 aut 
700 1 |a Zhang, Quanzhou  |e verfasserin  |4 aut 
700 1 |a Zhang, Zhenbao  |e verfasserin  |4 aut 
700 1 |a Huang, Langhuan  |e verfasserin  |4 aut 
700 1 |a Zhang, Jingxian  |e verfasserin  |4 aut 
700 1 |a Xiong, Yongqiang  |e verfasserin  |4 aut 
700 1 |a Tan, Shaozao  |e verfasserin  |4 aut 
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