|
|
|
|
| LEADER |
01000caa a22002652 4500 |
| 001 |
NLM291474470 |
| 003 |
DE-627 |
| 005 |
20250224114155.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
231225s2019 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1002/adma.201807226
|2 doi
|
| 028 |
5 |
2 |
|a pubmed25n0971.xml
|
| 035 |
|
|
|a (DE-627)NLM291474470
|
| 035 |
|
|
|a (NLM)30516862
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Chao, Yuguang
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a Ultrathin Visible-Light-Driven Mo Incorporating In2 O3 -ZnIn2 Se4 Z-Scheme Nanosheet Photocatalysts
|
| 264 |
|
1 |
|c 2019
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Completed 04.02.2019
|
| 500 |
|
|
|a Date Revised 30.09.2020
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status PubMed-not-MEDLINE
|
| 520 |
|
|
|a © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
|
| 520 |
|
|
|a Inspired by natural photosynthesis, the design of new Z-scheme photocatalytic systems is very promising for boosting the photocatalytic performance of H2 production and CO2 reduction; however, until now, the direct synthesis of efficient Z-scheme photocatalysts remains a grand challenge. Herein, it is demonstrated that an interesting Z-scheme photocatalyst can be constructed by coupling In2 O3 and ZnIn2 Se4 semiconductors based on theoretical calculations. Experimentally, a class of ultrathin In2 O3 -ZnIn2 Se4 (denoted as In2 O3 -ZISe) spontaneous Z-scheme nanosheet photocatalysts for greatly enhancing photocatalytic H2 production is made. Furthermore, Mo atoms are incorporated in the Z-scheme In2 O3 -ZISe nanosheet photocatalyst by forming the MoSe bond, confirmed by X-ray photoelectron spectroscopy, in which the formed MoSe2 works as cocatalyst of the Z-scheme photocatalyst. As a consequence, such a unique structure of In2 O3 -ZISe-Mo makes it exhibit 21.7 and 232.6 times higher photocatalytic H2 evolution activity than those of In2 O3 -ZnIn2 Se4 and In2 O3 nanosheets, respectively. Moreover, In2 O3 -ZISe-Mo is also very stable for photocatalytic H2 production by showing almost no activity decay for 16 h test. Ultraviolet-visible diffuse reflectance spectra, photoluminescence spectroscopy, transient photocurrent spectra, and electrochemical impedance spectroscopy reveal that the enhanced photocatalytic performance of In2 O3 -ZISe-Mo is mainly attributed to its widened photoresponse range and effective carrier separation because of its special structure
|
| 650 |
|
4 |
|a Journal Article
|
| 650 |
|
4 |
|a Z-scheme
|
| 650 |
|
4 |
|a ZnIn2Se4
|
| 650 |
|
4 |
|a nanosheets
|
| 650 |
|
4 |
|a photocatalysis
|
| 700 |
1 |
|
|a Zhou, Peng
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Li, Na
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Lai, Jianping
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Yang, Yong
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Zhang, Yelong
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Tang, Yonghua
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Yang, Wenxiu
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Du, Yaping
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Su, Dong
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Tan, Yisheng
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Guo, Shaojun
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 31(2019), 5 vom: 18. Feb., Seite e1807226
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
|
| 773 |
1 |
8 |
|g volume:31
|g year:2019
|g number:5
|g day:18
|g month:02
|g pages:e1807226
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1002/adma.201807226
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_350
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 31
|j 2019
|e 5
|b 18
|c 02
|h e1807226
|