Ultrathin Visible-Light-Driven Mo Incorporating In2 O3 -ZnIn2 Se4 Z-Scheme Nanosheet Photocatalysts
© 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
| Veröffentlicht in: | Advanced materials (Deerfield Beach, Fla.). - 1998. - 31(2019), 5 vom: 18. Feb., Seite e1807226 |
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| Weitere Verfasser: | , , , , , , , , , , |
| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2019
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| Zugriff auf das übergeordnete Werk: | Advanced materials (Deerfield Beach, Fla.) |
| Schlagworte: | Journal Article Z-scheme ZnIn2Se4 nanosheets photocatalysis |
| Zusammenfassung: | © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. Inspired by natural photosynthesis, the design of new Z-scheme photocatalytic systems is very promising for boosting the photocatalytic performance of H2 production and CO2 reduction; however, until now, the direct synthesis of efficient Z-scheme photocatalysts remains a grand challenge. Herein, it is demonstrated that an interesting Z-scheme photocatalyst can be constructed by coupling In2 O3 and ZnIn2 Se4 semiconductors based on theoretical calculations. Experimentally, a class of ultrathin In2 O3 -ZnIn2 Se4 (denoted as In2 O3 -ZISe) spontaneous Z-scheme nanosheet photocatalysts for greatly enhancing photocatalytic H2 production is made. Furthermore, Mo atoms are incorporated in the Z-scheme In2 O3 -ZISe nanosheet photocatalyst by forming the MoSe bond, confirmed by X-ray photoelectron spectroscopy, in which the formed MoSe2 works as cocatalyst of the Z-scheme photocatalyst. As a consequence, such a unique structure of In2 O3 -ZISe-Mo makes it exhibit 21.7 and 232.6 times higher photocatalytic H2 evolution activity than those of In2 O3 -ZnIn2 Se4 and In2 O3 nanosheets, respectively. Moreover, In2 O3 -ZISe-Mo is also very stable for photocatalytic H2 production by showing almost no activity decay for 16 h test. Ultraviolet-visible diffuse reflectance spectra, photoluminescence spectroscopy, transient photocurrent spectra, and electrochemical impedance spectroscopy reveal that the enhanced photocatalytic performance of In2 O3 -ZISe-Mo is mainly attributed to its widened photoresponse range and effective carrier separation because of its special structure |
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| Beschreibung: | Date Completed 04.02.2019 Date Revised 30.09.2020 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 1521-4095 |
| DOI: | 10.1002/adma.201807226 |