Probing the Physical Origin of Anisotropic Thermal Transport in Black Phosphorus Nanoribbons

© 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Détails bibliographiques
Publié dans:Advanced materials (Deerfield Beach, Fla.). - 1998. - 30(2018), 50 vom: 15. Dez., Seite e1804928
Auteur principal: Zhao, Yunshan (Auteur)
Autres auteurs: Zhang, Gang, Nai, Mui Hoon, Ding, Guangqian, Li, Dengfeng, Liu, Yi, Hippalgaonkar, Kedar, Lim, Chwee Teck, Chi, Dongzhi, Li, Baowen, Wu, Jing, Thong, John T L
Format: Article en ligne
Langue:English
Publié: 2018
Accès à la collection:Advanced materials (Deerfield Beach, Fla.)
Sujets:Journal Article Young's modulus anisotropy black phosphorus electron beam technique first-principles calculations thermal conductivity
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520 |a Black phosphorus (BP) has emerged as a promising candidate for next-generation electronics and optoelectronics among the 2D family materials due to its extraordinary electrical/optical/optoelectronic properties. Interestingly, BP shows strong anisotropic transport behavior because of its puckered honeycomb structure. Previous studies have demonstrated the thermal transport anisotropy of BP and theoretically attribute this to the anisotropy in both the phonon dispersion relation and the phonon relaxation time. However, the exact origin of such strong anisotropy lacks clarity and has yet to be proven experimentally. Here, the thermal transport anisotropy of BP nanoribbons is probed by an electron beam technique. Direct evidence is provided that the origin of this anisotropy is dominated by the anisotropic phonon group velocity, verified by Young's modulus measurements along different directions. It turns out that the ratio of the thermal conductivity between zigzag (ZZ) and armchair (AC) ribbons is almost same as that of the corresponding Young modulus values. The results from first-principles calculation are consistent with this experimental observation, where the anisotropic phonon group velocity between ZZ and AC is shown. These results provide fundamental insight into the anisotropic thermal transport in low-symmetry crystals 
650 4 |a Journal Article 
650 4 |a Young's modulus 
650 4 |a anisotropy 
650 4 |a black phosphorus 
650 4 |a electron beam technique 
650 4 |a first-principles calculations 
650 4 |a thermal conductivity 
700 1 |a Zhang, Gang  |e verfasserin  |4 aut 
700 1 |a Nai, Mui Hoon  |e verfasserin  |4 aut 
700 1 |a Ding, Guangqian  |e verfasserin  |4 aut 
700 1 |a Li, Dengfeng  |e verfasserin  |4 aut 
700 1 |a Liu, Yi  |e verfasserin  |4 aut 
700 1 |a Hippalgaonkar, Kedar  |e verfasserin  |4 aut 
700 1 |a Lim, Chwee Teck  |e verfasserin  |4 aut 
700 1 |a Chi, Dongzhi  |e verfasserin  |4 aut 
700 1 |a Li, Baowen  |e verfasserin  |4 aut 
700 1 |a Wu, Jing  |e verfasserin  |4 aut 
700 1 |a Thong, John T L  |e verfasserin  |4 aut 
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773 1 8 |g volume:30  |g year:2018  |g number:50  |g day:15  |g month:12  |g pages:e1804928 
856 4 0 |u http://dx.doi.org/10.1002/adma.201804928  |3 Volltext 
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