Inhibiting Reductive Elimination as an Intramolecular Disulfide Dramatically Enhances the Thermal Stability of SAMs on Gold Derived from Bidentate Adsorbents

The bidentate aromatic adsorbate, 5-(octadecyloxy)-1,3-benzenedimethanethiol (R1ArmDT), with a specific design of extended S-S distance and a geometric constraint to resist cyclic disulfide formation was synthesized. The film formation and thermal stability of self-assembled monolayers (SAMs) derive...

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Publié dans:Langmuir : the ACS journal of surfaces and colloids. - 1985. - 34(2018), 23 vom: 12. Juni, Seite 6645-6652
Auteur principal: Rittikulsittichai, Supachai (Auteur)
Autres auteurs: Park, Chul Soon, Marquez, Maria D, Jamison, Andrew C, Frank, Thomas, Wu, Chia-Hua, Wu, Judy I, Lee, T Randall
Format: Article en ligne
Langue:English
Publié: 2018
Accès à la collection:Langmuir : the ACS journal of surfaces and colloids
Sujets:Journal Article Research Support, U.S. Gov't, Non-P.H.S.