Enhanced adsorption of ciprofloxacin by KOH modified biochar derived from potato stems and leaves

Potato stems and leaves biochar (PB) was prepared by pyrolysis at a temperature of 500°C under anoxic conditions. In order to strengthen the adsorption capacity, biochar was modified with alkaline solution (alkali modified biochar, APB). Two kinds of biochars were adopted as adsorbents to remove cip...

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Détails bibliographiques
Publié dans:Water science and technology : a journal of the International Association on Water Pollution Research. - 1986. - 77(2018), 3-4 vom: 15. Feb., Seite 1127-1136
Auteur principal: Li, Ruining (Auteur)
Autres auteurs: Wang, Zhaowei, Guo, Jialei, Li, Yan, Zhang, Hanyu, Zhu, Junmin, Xie, Xiaoyun
Format: Article en ligne
Langue:English
Publié: 2018
Accès à la collection:Water science and technology : a journal of the International Association on Water Pollution Research
Sujets:Journal Article Anti-Bacterial Agents Water Pollutants, Chemical biochar Charcoal 16291-96-6 Ciprofloxacin 5E8K9I0O4U Nitrogen N762921K75
Description
Résumé:Potato stems and leaves biochar (PB) was prepared by pyrolysis at a temperature of 500°C under anoxic conditions. In order to strengthen the adsorption capacity, biochar was modified with alkaline solution (alkali modified biochar, APB). Two kinds of biochars were adopted as adsorbents to remove ciprofloxacin (CIP) from aqueous solution. The adsorption behavior of CIP onto biochar before and after alkali modified including adsorption kinetics and isotherms were investigated. The effects of different factors (equilibrium time, pH, temperature and initial concentration) during the adsorption process were also investigated. Biochar samples were characterized by Fourier transform infrared (FTIR), scanning electron microscopy (SEM), and nitrogen adsorption-desorption isotherm. The results showed that the alkali treated biochar possessed more mesopores than raw biochar, and accordingly exhibited a more excellent adsorption performance (23.36 mg·g-1) than raw biochar. Hydrophobic interaction, hydrogen-bonding interaction, electrostatic interaction, and π - π interaction were the adsorption mechanisms for CIP uptake onto the two adsorbents
Description:Date Completed 15.08.2018
Date Revised 02.12.2018
published: Print
Citation Status MEDLINE
ISSN:0273-1223
DOI:10.2166/wst.2017.636