Analysis of the Surface Oxidation Process on Pt Nanoparticles on a Glassy Carbon Electrode by Angle-Resolved, Grazing-Incidence X-ray Photoelectron Spectroscopy
We have analyzed the surface oxidation process of Pt nanoparticles that were uniformly dispersed on a glassy carbon electrode (Pt/GC), which was adopted as a model of a practical Pt/C catalyst for fuel cells, in N2-purged 0.1 M HF solution by using angle-resolved, grazing-incidence X-ray photoelectr...
| Veröffentlicht in: | Langmuir : the ACS journal of surfaces and colloids. - 1985. - 33(2017), 36 vom: 12. Sept., Seite 8877-8882 |
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| Weitere Verfasser: | , , |
| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2017
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| Zugriff auf das übergeordnete Werk: | Langmuir : the ACS journal of surfaces and colloids |
| Schlagworte: | Journal Article Research Support, Non-U.S. Gov't |
| Zusammenfassung: | We have analyzed the surface oxidation process of Pt nanoparticles that were uniformly dispersed on a glassy carbon electrode (Pt/GC), which was adopted as a model of a practical Pt/C catalyst for fuel cells, in N2-purged 0.1 M HF solution by using angle-resolved, grazing-incidence X-ray photoelectron spectroscopy combined with an electrochemical cell (EC-ARGIXPS). Positive shifts in the binding energies of Pt 4f spectra were clearly observed for the surface oxidation of Pt nanoparticles at potentials E > 0.7 V vs RHE, followed by a bulk oxidation of Pt to form Pt(II) at E > 1.1 V. Three types of oxygen species (H2Oad, OHad, and Oad) were identified in the O 1s spectra. It was found for the first time that the surface oxidation process of the Pt/GC electrode at E < ca. 0.8 V (OHad formation) is similar to that of a Pt(111) single-crystal electrode, whereas that in the high potential region (Oad formation) resembles that of a Pt(110) surface or polycrystalline Pt film |
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| Beschreibung: | Date Completed 23.07.2018 Date Revised 23.07.2018 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 1520-5827 |
| DOI: | 10.1021/acs.langmuir.7b01446 |