Fate of metals and emissions of organic pollutants from torrefaction of waste wood, MSW, and RDF
Copyright © 2017 Elsevier Ltd. All rights reserved.
Veröffentlicht in: | Waste management (New York, N.Y.). - 1999. - 68(2017) vom: 15. Okt., Seite 646-652 |
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1. Verfasser: | |
Weitere Verfasser: | , , , |
Format: | Online-Aufsatz |
Sprache: | English |
Veröffentlicht: |
2017
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Zugriff auf das übergeordnete Werk: | Waste management (New York, N.Y.) |
Schlagworte: | Journal Article Fuel upgrading PCDD PCDF Thermochemical conversion Benzofurans Metals Solid Waste Chlorine 4R7X1O2820 |
Zusammenfassung: | Copyright © 2017 Elsevier Ltd. All rights reserved. Torrefaction of municipal solid waste (MSW), refuse-derived fuel (RDF), and demolition and construction wood (DC) was performed at 220°C and a residence time of 90min in a bench-scale reactor. The levels of toxic polychlorinated dibenzo-p-dioxins (PCDD) and dibenzofurans (PCDF) contained in emission from the torrefaction process were evaluated. In addition, main ash-forming elements and trace metals in the raw feedstock and char were determined. The use of MSW in fuel blends with DC resulted in lower PCDD and PCDF emissions after torrefaction, compared with the RDF blends. The migration of chlorine from the feedstock to the gas phase reduces the chlorine content of the char which may reduce the risk of alkali chloride-corrosion in char combustion. However, trace metals catalytically active in the formation of PCDD and PCDF remain in the char, thereby may promote PCDD and PCDF formation during subsequent char combustion for energy recovery; this formation is less extensive than when the feedstock is used |
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Beschreibung: | Date Completed 17.01.2018 Date Revised 02.12.2018 published: Print-Electronic Citation Status MEDLINE |
ISSN: | 1879-2456 |
DOI: | 10.1016/j.wasman.2017.06.017 |