Pt/ZnOC Nanocable with Dual-Enhanced Photocatalytic Performance and Superior Photostability

To improve the photocatalytic activity and photostability of ZnO, a novel cable-like Pt/ZnOC composite is successfully fabricated by coating a 3-5 nm hydrothermal carbon (HTC) layer on the surface of the Pt nanoparticle-modified ZnO nanowire. After investigating the optical and photoelectrochemical...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1985. - 33(2017), 18 vom: 09. Mai, Seite 4452-4460
1. Verfasser: Zhang, Peng (VerfasserIn)
Weitere Verfasser: Chen, Yang, Yang, Xiaoyan, Gui, Jianzhou, Li, Yi, Peng, Hailong, Liu, Dan, Qiu, Jieshan
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2017
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, Non-U.S. Gov't
Beschreibung
Zusammenfassung:To improve the photocatalytic activity and photostability of ZnO, a novel cable-like Pt/ZnOC composite is successfully fabricated by coating a 3-5 nm hydrothermal carbon (HTC) layer on the surface of the Pt nanoparticle-modified ZnO nanowire. After investigating the optical and photoelectrochemical performance in detail, it is found that the Pt/ZnO@C nanocable shows a dual-enhanced migration efficiency for the photoinduced surface electrons, distributing to the modified Pt nanoparticles and the coated HTC layer. Consequently, the Pt/ZnO@C nanocable exhibits a dual-enhanced photocatalytic activity for the degradation of various organic pollutants under the UV light irradiation. The coated HTC layer can also play a role in suspending the ZnO photocorrosion and significantly improves the photostability of the Pt/ZnO@C nanocable. Furthermore, the photocatalysis and photocorrosion mechanism of the Pt/ZnO@C nanocable is proposed and discussed in terms of its structural feature and photoelectrochemical property. The resultant Pt/ZnO@C nanocable with the unique HTC layer-coated structure will probably stimulate to design and synthesize more HTC-hybridized composites with a superior photocatalytic or photoelectrocatalytic performance
Beschreibung:Date Completed 10.07.2018
Date Revised 10.07.2018
published: Print-Electronic
Citation Status PubMed-not-MEDLINE
ISSN:1520-5827
DOI:10.1021/acs.langmuir.7b00995