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|a DE-627
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|e rakwb
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|a eng
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| 100 |
1 |
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|a Zitz, Rainer
|e verfasserin
|4 aut
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| 245 |
1 |
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|a Metalated Oligosilanylstibines
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| 264 |
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|c 2015
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| 336 |
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|a Text
|b txt
|2 rdacontent
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|a ohne Hilfsmittel zu benutzen
|b n
|2 rdamedia
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| 338 |
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|a Band
|b nc
|2 rdacarrier
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| 500 |
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|a Date Revised 01.10.2020
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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| 520 |
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|a The reaction of a cyclic disilylated bromostibine with magnesium yields a rare example of a magnesium stibide that can be silylated with trimethylchlorosilane. Reaction of the thus-obtained trisilylated stibine with potassium tert-butoxide gives a potassium stibide in a clean reaction. Attempts to obtain an antimony-containing oligosilanide did not lead to the expected compound but to another potassium stibide, which presumably forms from the initially formed silanide by a 1,2-silyl shift. The synthetic potential of the obtained stibides to serve as building blocks could be shown by the preparation of stibylated zircono- and hafnocenes
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|a Journal Article
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1 |
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|a Baumgartner, Judith
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Marschner, Christoph
|e verfasserin
|4 aut
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| 773 |
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8 |
|i Enthalten in
|t Organometallics
|d 1998
|g 34(2015), 8 vom: 27. Apr., Seite 1431-1439
|w (DE-627)NLM098167103
|x 0276-7333
|7 nnas
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| 773 |
1 |
8 |
|g volume:34
|g year:2015
|g number:8
|g day:27
|g month:04
|g pages:1431-1439
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|d 34
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