Comparison of 1H-19F two-dimensional NMR scalar coupling correlation pulse sequences
Copyright © 2014 John Wiley & Sons, Ltd.
| Publié dans: | Magnetic resonance in chemistry : MRC. - 1985. - 52(2014), 4 vom: 30. Apr., Seite 183-9 |
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| Auteur principal: | |
| Autres auteurs: | , |
| Format: | Article en ligne |
| Langue: | English |
| Publié: |
2014
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| Accès à la collection: | Magnetic resonance in chemistry : MRC |
| Sujets: | Journal Article 19F 1H 2D NMR 2JFF strong coupling HETCOR HMBC HMQC HSQC NMR |
| Résumé: | Copyright © 2014 John Wiley & Sons, Ltd. The effectiveness of hetero-COSY, HETCOR, HMQC, and HSQC two-dimensional NMR pulse sequences for detection of (19)F-(1)H correlations by scalar coupling was evaluated on monofluorinated and polyfluorinated test compounds. All four of these sequences were effective in observing (1)H-(19)F correlations, using either (19) F or (1)H as the observe nucleus. All four sequences were amenable, to some degree, to adjustment to observe larger or smaller couplings preferentially. A 1/2J echo filter was effectively applied to remove artifacts from (2)JFF strong coupling. The HETCOR experiments afforded the best overall combination of sensitivity, resolution and selectivity for JHF |
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| Description: | Date Completed 23.10.2014 Date Revised 07.03.2014 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 1097-458X |
| DOI: | 10.1002/mrc.4052 |