Electrostatic repulsion-controlled formation of polydopamine-gold Janus particles

Polydopamine (PDA)-Au Janus particles were obtained by simply adding HAuCl(4) to a PDA particle suspension, prepared via self-polymerization of dopamine in basic solution at room temperature. The structures of the PDA-Au particles are readily controlled by electrostatic repulsion between the constit...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 28(2012), 36 vom: 11. Sept., Seite 13060-5
1. Verfasser: Xu, Haolan (VerfasserIn)
Weitere Verfasser: Liu, Xiaokong, Su, Ge, Zhang, Bin, Wang, Dayang
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2012
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Chlorides Gold Compounds Indoles Polymers polydopamine Gold 7440-57-5 gold tetrachloride, acid 8H372EGX3V
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520 |a Polydopamine (PDA)-Au Janus particles were obtained by simply adding HAuCl(4) to a PDA particle suspension, prepared via self-polymerization of dopamine in basic solution at room temperature. The structures of the PDA-Au particles are readily controlled by electrostatic repulsion between the constituent particles, which can be realized simply via adjusting the environmental pH. PDA-Au Janus particles are formed only in a narrow pH range of 2.5-3.0 due to the properly enhanced electrostatic repulsion between the Au particles growing on as-prepared PDA particles and between the Au and PDA particles. The obtained PDA-Au Janus particles can become interfacially active and self-assemble at oil/water interfaces as a result of spatially well-separated hydrophilic (PDA) and hydrophobic (Au) domains on the surfaces, reminiscent of amphiphilic molecules 
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700 1 |a Zhang, Bin  |e verfasserin  |4 aut 
700 1 |a Wang, Dayang  |e verfasserin  |4 aut 
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