Synthesis of Oligosilanyl Compounds of Group 4 Metallocenes with the Oxidation State +3

Recently, we showed that titanocene silyls are much more stable with Ti in the oxidation state +3. The current study demonstrates that analogous Zr and Hf compounds can also be obtained by reaction of a suitable metalate precursor with an oligosilanyl dianion. As the obtained complexes formally poss...

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Détails bibliographiques
Publié dans:Organometallics. - 1998. - 31(2012), 11 vom: 11. Juni, Seite 4309-4319
Auteur principal: Arp, Henning (Auteur)
Autres auteurs: Zirngast, Michaela, Marschner, Christoph, Baumgartner, Judith, Rasmussen, Kenneth, Zark, Patrick, Müller, Thomas
Format: Article
Langue:English
Publié: 2012
Accès à la collection:Organometallics
Sujets:Journal Article