Characterisation of the recalcitrant organic compounds in leachates formed during the anaerobic biodegradation of waste

This study investigates the use of UV absorption and fluorescence spectroscopy to assess the early development of recalcitrant organic compounds in leachates formed during the anaerobic biodegradation of municipal solid waste. Biochemical methane potential tests were carried out on fresh waste (FW)...

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Détails bibliographiques
Publié dans:Water science and technology : a journal of the International Association on Water Pollution Research. - 1986. - 64(2011), 2 vom: 11., Seite 311-9
Auteur principal: Yunus, Anika (Auteur)
Autres auteurs: Smallman, David J, Stringfellow, Anne, Beaven, Richard, Powrie, William
Format: Article
Langue:English
Publié: 2011
Accès à la collection:Water science and technology : a journal of the International Association on Water Pollution Research
Sujets:Journal Article Organic Chemicals Water Pollutants, Chemical
Description
Résumé:This study investigates the use of UV absorption and fluorescence spectroscopy to assess the early development of recalcitrant organic compounds in leachates formed during the anaerobic biodegradation of municipal solid waste. Biochemical methane potential tests were carried out on fresh waste (FW) and composted waste (CW) over a period of 150 days and leachates produced from the degradation of two wastes were analysed for humic-like (H-L) and fulvic-like (F-L) structures by UV spectroscopy and fluorescence excitation-emission-matrix analyses. During anaerobic biodegradation, the synthesis and utilization of H-L and F-L structures in the leachates over time was indicative of the generation of the recalcitrant organic compounds. The results obtained from UV absorption and fluorescence spectroscopy suggested that CW leachates resulted in a higher concentration and more condensed form of recalcitrant H-L and F-L molecules than FW leachates. These findings demonstrate how fluorescence and UV absorption spectroscopy can be used as an indicator for monitoring the evolution of recalcitrant organic compounds (H-L and F-L substances) in leachates formed at different stages of waste biodegradation
Description:Date Completed 06.12.2011
Date Revised 18.09.2019
published: Print
Citation Status MEDLINE
ISSN:0273-1223