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231224s2011 xx |||||o 00| ||eng c |
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|a 10.1002/mrc.2774
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|a eng
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|a Kříž, Jaroslav
|e verfasserin
|4 aut
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|a Interaction of hydrated protons with octyl-phenyl-N,N-diisobutylcarbamoylmethyl phosphine oxide (CMPO)
|b NMR and theoretical study
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|c 2011
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
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|2 rdacarrier
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|a Date Completed 04.05.2012
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|a Date Revised 20.09.2011
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|a published: Print-Electronic
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|a Citation Status MEDLINE
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|a Copyright © 2011 John Wiley & Sons, Ltd.
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|a Interaction of octyl-phenyl-N,N-diisobutylcarbamoylmethylphosphine oxide (CMPO, the 'classical' rare metal extraction agent) with fully ionized hydrated protons (HP) was studied in acetonitrile-d(3) using (1)H, (13)C, (31)P NMR, PFG NMR and magnetic relaxation. The experimental results were confronted with high-precision ab initio DFT calculations. Relative chemical shifts of NMR signals of CMPO (0.01 mol/L) under the presence of HP in the molar ratio β = 0-2.0 mol/mol show binding between CMPO and HP. Self-diffusion measurements using (1)H PFG NMR demonstrate that larger complexes with higher content of CMPO are generally formed at β < 0.75. Analyzing the collective dependence of (13)C and (31)P NMR chemical shifts on β by the use of program LETAGROP, we obtained very good fitting for the assumed coexistence of two complexes (CMPO)(2)·HP (C(2)) and CMPO.HP (C(1)). The logarithms of the respective stabilization constants log K(i) were found to be 7.518 (C(2)) and 4.581 (C(1)). The system dynamics was studied by measuring the transverse (1)H NMR relaxation using CPMG sequence with varying delays t(p) between the π pulses in the mixtures with β = 0.4-0.8. The following exchange correlation times were obtained: τ(10) = 2.35 × 10(-5), τ(20) = 0.82 × 10(-4), τ(21) = 0.45 × 10(-3) s. The DFT calculations support the conclusion that the complexes C(1) and C(2) are the main species in the mixtures of CMPO with HP. They also agree with the NMR and FTIR observation that the main site to which H(3) O(+) is bound is the P=O group, whereas the amide group does not form a strong bond with the ion when excess water molecules are present
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|a Journal Article
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|a Research Support, Non-U.S. Gov't
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|a (N,N-diisobutylcarbamoylmethyl)phenyloctylphosphine oxide
|2 NLM
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|a Phosphines
|2 NLM
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|a Protons
|2 NLM
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|a Dybal, Jiří
|e verfasserin
|4 aut
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|a Makrlík, Emanuel
|e verfasserin
|4 aut
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| 700 |
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|a Vaňura, Petr
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Magnetic resonance in chemistry : MRC
|d 1985
|g 49(2011), 10 vom: 30. Okt., Seite 617-26
|w (DE-627)NLM098179667
|x 1097-458X
|7 nnns
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|g volume:49
|g year:2011
|g number:10
|g day:30
|g month:10
|g pages:617-26
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|u http://dx.doi.org/10.1002/mrc.2774
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