|
|
|
|
| LEADER |
01000caa a22002652c 4500 |
| 001 |
NLM207796343 |
| 003 |
DE-627 |
| 005 |
20250212171448.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
231224s2011 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1021/la2007815
|2 doi
|
| 028 |
5 |
2 |
|a pubmed25n0693.xml
|
| 035 |
|
|
|a (DE-627)NLM207796343
|
| 035 |
|
|
|a (NLM)21526834
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Porus, Mariya
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a Zipper and layer-by-layer assemblies of artificial photosystems analyzed by combining optical and piezoelectric surface techniques
|
| 264 |
|
1 |
|c 2011
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Completed 23.09.2011
|
| 500 |
|
|
|a Date Revised 31.05.2011
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status PubMed-not-MEDLINE
|
| 520 |
|
|
|a Quartz crystal microbalance (QCM) and surface plasmon resonance (SPR) were used to study zipper and layer-by-layer multilayer assemblies of artificial photosystems based on naphthalenediimides (NDIs) attached to an oligophenylethynyl (OPE-NDI) or p-oligophenyl (POP-NDI) backbone in dry and wet state. For the most interesting OPE-NDI zipper, one obtains for the dry film a monolayer thickness of 1.85 nm and a density of 1.58 g/cm(3), while the wet film has a larger monolayer thickness of 3.6 nm with a water content of 36%. The dry thickness of a monolayer in OPE-NDI zippers corresponds to about one-half of the length of the OPE scaffold in agreement with the proposed structure of the zipper. The low water content of the OPE-NDI films confirms their compact structure. The dry monolayer thickness of the POP-NDI films of 1.45 nm is smaller than that for the OPE-NDI films, which is probably related to a tilt of the POP scaffolds within the adsorbed layer. The POP-NDI films swell in water much more substantially, suggesting a much more open structure. These features are in excellent agreement with the better photophysical performance of the OPE-NDI assemblies when compared to the POP-NDI films
|
| 650 |
|
4 |
|a Journal Article
|
| 700 |
1 |
|
|a Maroni, Plinio
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Bhosale, Rajesh
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Sakai, Naomi
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Matile, Stefan
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Borkovec, Michal
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1985
|g 27(2011), 11 vom: 07. Juni, Seite 7213-21
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnas
|
| 773 |
1 |
8 |
|g volume:27
|g year:2011
|g number:11
|g day:07
|g month:06
|g pages:7213-21
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1021/la2007815
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_22
|
| 912 |
|
|
|a GBV_ILN_350
|
| 912 |
|
|
|a GBV_ILN_721
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 27
|j 2011
|e 11
|b 07
|c 06
|h 7213-21
|