Removal of manganese ions from synthetic groundwater by oxidation using KMnO(4) and the characterization of produced MnO(2) particles

The aim of this study is to investigate the conditions for the removal of manganese ions from synthetic groundwater by oxidation using KMnO(4) to keep the concentration below the allowed level (0.05 mg/L). The process includes low-level aeration and addition of KMnO(4) in a Jar test system with Mn(2...

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Publié dans:Water science and technology : a journal of the International Association on Water Pollution Research. - 1986. - 62(2010), 8 vom: 21., Seite 1719-26
Auteur principal: Phatai, P (Auteur)
Autres auteurs: Wittayakun, J, Grisdanurak, N, Chen, W H, Wan, M W, Kan, C C
Format: Article en ligne
Langue:English
Publié: 2010
Accès à la collection:Water science and technology : a journal of the International Association on Water Pollution Research
Sujets:Journal Article Research Support, Non-U.S. Gov't Cations, Divalent Manganese Compounds Oxides Water Pollutants, Chemical Potassium Permanganate 00OT1QX5U4 Manganese 42Z2K6ZL8P plus... manganese dioxide TF219GU161
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Résumé:The aim of this study is to investigate the conditions for the removal of manganese ions from synthetic groundwater by oxidation using KMnO(4) to keep the concentration below the allowed level (0.05 mg/L). The process includes low-level aeration and addition of KMnO(4) in a Jar test system with Mn(2 + ) concentration of 0.50 mg/L, similar to that of natural groundwater in Taiwan. Different parameters such us aeration-pH, oxidant dose, and stirring speed were studied. Aeration alone was not sufficient to remove Mn(2 + ) ions completely even when the pH was increased. When a stoichiometric amount of KMnO(4) (0.96 mg/L) was used, a complete Mn(2 + ) removal was achieved within 15 min at an optimum pH of 8.0. As the amount of KMnO(4) was doubled, lower removal efficiency was obtained because the oxidant also generated manganese ions. The removal of Mn(2 + ) ions could be completed at pH 9.0 using an oxidant dose of 0.48 mg/L because Mn(2 + ) could be sorbed onto the MnO(2) particles. Finally, The MnO(2) particles were characterized using scanning electron microscopy (SEM) and energy dispersive X-ray analysis (EDX)
Description:Date Completed 03.01.2011
Date Revised 19.11.2015
published: Print
Citation Status MEDLINE
ISSN:0273-1223
DOI:10.2166/wst.2010.462