Diazirine-modified gold nanoparticle : template for efficient photoinduced interfacial carbene insertion reactions

Photolysis of a 3-aryl-3-(trifluoromethyl)diazirine-modified monolayer-protected gold nanoparticles (2-C(12)MPNs), with a core size of 1.8 ± 0.3 nm, in the presence of model carbene trapping reagents leads to efficient, essentially quantitative, modification of the interface via carbene insertion re...

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Publié dans:Langmuir : the ACS journal of surfaces and colloids. - 1991. - 26(2010), 18 vom: 21. Sept., Seite 14958-64
Auteur principal: Ismaili, Hossein (Auteur)
Autres auteurs: Lee, Soo, Workentin, Mark S
Format: Article en ligne
Langue:English
Publié: 2010
Accès à la collection:Langmuir : the ACS journal of surfaces and colloids
Sujets:Journal Article Research Support, Non-U.S. Gov't Alkenes Ligands carbene 2465-56-7 Diazomethane 60A625P70P Gold 7440-57-5 plus... Methane OP0UW79H66